Using an organic acid as a universal anode for highly efficient Li-ion, Na-ion and K-ion batteries

Wang, Chuan; Tang, Wu; Yao, Zeyi; Chen, Yongzhen; Pei, Jingfang; Fan, Cong

doi:10.1016/j.orgel.2018.06.027

Cited by 80 publications

(47 citation statements)

References 39 publications

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“…In this case, the capacity contribution from carbons was estimated to be around7 .5 mAh g À1 (50 mA g À1 )a nd this value must be subtracted ( Figure S2). [16] Meanwhile, the charge-discharge potentials werec learly observed for Na 2 AQ26DS,w ith an averaged ischarge (reduction)p otential of around1 .7 Va nd an average charge (oxidation) potentialo f about 2V .…”

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confidence: 89%

“…Na 2 AQ26DSh as polyanionic character and each Na 2 AQ26DS molecule contains two OÀNa ionic bonds. [16] We also carriedo ut the solubility test for Na 2 AQ26DS (Figure 1b); Na 2 AQ26DS was totally soluble in H 2 Ow ith ac oncentration of 1.7 mg mL À1 at least. [14] Indeed, after proper optimization, Na 2 AQ26DS could deliver highly stable capacities of around1 20 mAh g À1 for 300 cycles at al ow current density of 50 mA g À1 and around 99 mAh g À1 for 1000 cycles at ah igh current density of 1Ag À1 ,w hich corre- sponds capacity retentions of 92 %a nd 76 %o fi ts theoretical value (C T = 130 mAh g À1 ), respectively.…”

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confidence: 99%

“…At the high current densities of 1o r2Ag À1 ,t he capacity values were still observedt ob e1 01 and 86 mAh g À1 ,r espectively,w hichi ndicates capacityr etentiono f7 8a nd 66 %o ft he theoretical value. [16] In summary,t he polyanionic organic electrode materials with strong ionic bonds are revealed to be highly stable in commono rganic solvents. a) Selectedc harge-discharge curves of Na2AQ26DS at ac urrent density of 50 mA g À1 .b)The long-termcycling profile at ac urrent density of 50 mA g À1 .c )The rate performance of Na2AQ26DS.d )The long-termc ycling profileo fNa2AQ26DS at ahighc urrent density of 1000 mA g À1 .Thepotential windoww as 1-3.5 VinN a-ion cells.…”

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confidence: 99%

“…[15] Na 2 AQ26DS can exhibit two-electron redox behavior in Na-ion batteries (Figure 1a), with at heoretical capacity of 130 mAh g À1 .A lthought he sulfonate groups endow Na 2 AQ26DS with two OÀNa ionic bonds, the theoretical capacity of Na 2 AQ26DS is below that of the parent 9,10-anthraquinone (AQ, 258 mAh g À1 ), because the substituent groups are redox inactive and only increase the molecular weight. [16] We also carriedo ut the solubility test for Na 2 AQ26DS (Figure 1b); Na 2 AQ26DS was totally soluble in H 2 Ow ith ac oncentration of 1.7 mg mL À1 at least. In contrast, Na 2 AQ26DS was found by direct eye observation to be very difficult to dissolvei n commono rganic electrolytes, such as ethylene carbonate (EC) or diethylcarbonate (DEC).…”

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confidence: 99%

“…Notably, the capacity contributionsf rom carbon additives (KB and CNTs) were negligible and calculated to be around7 ,6 .5, 6, and 5.5 mAh g À1 at currentd ensities of 100, 200,5 00, and 1000 mA g À1 under the same conditions ( Figure S2). [16] In summary,t he polyanionic organic electrode materials with strong ionic bonds are revealed to be highly stable in commono rganic solvents. The tested material-sodium9 ,10anthraquinone-2,6-disulfonate-gave rise to the specific capacities of around1 20 mAh g À1 over 300 cycles (50mAg À1 ) and around 99 mAh g À1 over 1000 cycles (1 Ag À1 )w ith the optimizede lectrolyte system in Na-ion batteries.…”

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confidence: 99%

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Highly Stable and High Rate‐Performance Na‐Ion Batteries Using Polyanionic Anthraquinone as the Organic Cathode

Tang

Ren

et al. 2019

ChemSusChem

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Sodium 9,10-anthraquinone-2,6-disulfonate (Na 2 AQ26DS), with polyanionic character and two OÀNa ionic bonds, is found to be ah ighly stable organic cathode in Na-ion batteries, delivering capacities of approximately 120 mAh g À1 for 300 cycles (50 mA g À1 )a nd around 99 mAh g À1 for 1000 cycles (1 Ag À1 ). These resultsa re the best performance reported to date for small-molecule, anthraquinone-basedo rganic cathodes in Li-, Na-, or K-ionbatteries.The rapidly-growing demands for electric vehicles anda"smart grid" require large-scale applicationso fr echargeable batteries.[1] Therefore, electrode materials in batteries that are low in cost, free of resourcel imitations, and environmentally friendly are highly desirable . [2] At present,r echargeable Li-ion batteries are approaching the ceiling of their energy density. [3] Moreover, the limited resources of Li (0.0017 wt %f or Li in the Earth's crust) and of the rare metals contained in cathodes, such as Ni, Co, Mn, also impedet heir large-scale application. [4] Organic electrode materials with extremelyl ow costs have attractedm ore and more attention as promisingn ext-generation energy-storagem aterials. More importantly,o rganic electrodes have been found capable to store abundant, cheap, and large-radius metal ions, such as Na + ,K + ,a nd Mg 2 + . [5] There are two main concerns for organic electrode materials under consideration for practical application. One is that organic electrode materials usually suffer from poor electronic conductivity and thus give unsatisfactory rate performance. [6] However,this problem can be largely solved by careful technological modifications. The other is that small-molecule organic materials, particularly for high-capacity organic cathodes, [7] show significant solubility in organic liquid electrolytes, [8] ultimately leadingt ot he poor cycling stability of organicb atteries.

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confidence: 89%

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confidence: 99%

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confidence: 99%

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confidence: 99%

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confidence: 99%

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Highly Stable and High Rate‐Performance Na‐Ion Batteries Using Polyanionic Anthraquinone as the Organic Cathode

Tang

Ren

et al. 2019

ChemSusChem

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Newborn Electrodes for K‐Ion Batteries

Rezaei

Rezaeian

Rahimpour

2020

Potassium‐Ion Batteries

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Advancements and Challenges in Potassium Ion Batteries: A Comprehensive Review

Rajagopalan

Tang

et al. 2020

Adv Funct Materials

702

401

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Demand for energy in day to day life is increasing exponentially. However, existing energy storage technologies like lithium ion batteries cannot stand alone to fulfill future needs. In this regard, potassium ion batteries (KIBs) that utilize K ions in their charge storage mechanism have attracted considerable attention due to their unique properties and are therefore established as one of the future battery systems of interest among the scientific community. Nevertheless, the development and identification of appropriate electrode materials is very essential for practical applications. This review features the current development in KIBs electrode and electrolyte materials, the present challenges facing this technology (in the commercial aspect), and future aspects to develop fully functional KIBs. The potassium storage mechanisms, evolution of the KIBs, and the advantages and disadvantages of each category of materials are included. Additionally, various approaches to enhance the electrochemical performances of KIBs are also discussed. This review is not only an amalgamation of different viewpoints in literature, but also contains concise perspectives and strategies. Moreover, the potential emergence of a novel class of K‐based dual ion batteries is also analyzed for the first time.

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Using an organic acid as a universal anode for highly efficient Li-ion, Na-ion and K-ion batteries

Cited by 80 publications

References 39 publications

Highly Stable and High Rate‐Performance Na‐Ion Batteries Using Polyanionic Anthraquinone as the Organic Cathode

Highly Stable and High Rate‐Performance Na‐Ion Batteries Using Polyanionic Anthraquinone as the Organic Cathode

Newborn Electrodes for K‐Ion Batteries

Advancements and Challenges in Potassium Ion Batteries: A Comprehensive Review

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