In the western USA,
one legacy of historic mining is drainage of
acidic, metal-rich water generated by exposure to oxygen of sulfide
minerals in mine workings, referred to as acid mine drainage (AMD).
Streams receiving AMD and natural acid rock drainage (ARD) have a
low pH, high dissolved metal concentrations, and extensive streambed
oxide deposits. Recently, enhanced ARD generation in the Snake River
watershed in the Rocky Mountains has been shown to be associated with
warmer summer air temperatures, which has been attributed to expanding
weathering fronts that promote oxidation due to earlier drying of
shallow soils. In mountain watersheds where complex orogeny disseminated
minerals throughout the landscape, weathering processes may also mobilize
rare earth elements (REEs). We report that in the Snake River REEs
are currently distributed in streams at concentrations ranging from
1 to 100 μg/L. Further, analysis of archived sample indicates
that REE increases over time are also associated with increased summer
air temperatures. In downstream reaches where the Snake River discharges
into a water supply reservoir, colloidal and particulate metal oxides
are abundant and sorptive processes may influence REE speciation.
We also show that REEs accumulate in benthic invertebrates at concentrations
comparable to toxic metals associated with ARD.