2012) Preparation of coagulant from red mud and semi-product of polyaluminum chloride for removal of phosphate from water, Desalination and Water Treatment, 40:1-3, 153-158,
A B S T R AC TTraditionally, calcium aluminate, caustic soda, lime or aluminum slag was employed as alkali for basicity adjustment in the production of polyaluminum chloride (PACl). In this work, red mud (RM), a highly alkaline waste from alumina industry, was utilized instead of the traditional alkali. A composite coagulant (RMPACl) was prepared from RM and the semi-product of polyaluminum chloride (ACl). Important factors for preparation, such as RM/ACl ratio, reaction temperature and reaction time, were investigated and optimized to be as follows: RM/ACl ratio of 0.25 (w v −1 ), reaction temperature of 80°C and reaction time of 4 h. The results of coagulation tests showed that RMPACl exhibited better performance than PACl for removal of phosphate. The optimum coagulation pH range of RMPACl was found to be 6.0-8.5. High phosphate removal effi ciency (>94.9%) was achieved by dosing RMPACl at the dosage of 147.5 mg l −1 . Therefore, RMPACl was considered as a low-cost coagulant, which possessed a good coagulation performance for removal of phosphate.