Utilization of ferric groundwater treatment residuals for inorganic-organic hybrid biosorbent preparation and its use for vanadium removal

Zhang, Ruichi; Leiviskä, Tiina; Tanskanen, Juha; Gao, Baoyu; Yue, Qinyan

doi:10.1016/j.cej.2018.12.122

Cited by 53 publications

(23 citation statements)

References 52 publications

(70 reference statements)

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“…This confirmed that Fe–O and Fe–OH groups acted as the adsorption sites. Slight shifts of the Fe 2p 3/2 and Fe 2p 1/2 peaks towards a higher binding energy were also found earlier by Zhang et al. (2019) for the ferric water treatment residuals after the adsorption of vanadium.…”

Section: Resultssupporting

confidence: 79%

“…The O 1s spectrum of SG dye adsorbed GWTW shows that BE of oxygen of the hydroxy group decreased after the dye adsorption. This change can be due to the interaction between the hydroxyl groups of GWTW and SG dye anions ( Zhang et al., 2019 ). There are two peaks in high – resolution Ca 2p spectra (Figure 3S) at 347.52 (2p 3/2 ) and 351.22 eV (2p 1/2 ), which can be attributed to CaCO 3 ( Li and Zeng, 2012 ; Ni and Ratner, 2008 ).…”

Section: Resultsmentioning

confidence: 99%

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Sustainable removal of anodized aluminum dye by groundwater treatment waste: experimental and modeling

Sodaitienė

Gefenienė

Kaušpėdienė

et al. 2021

Heliyon

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Groundwater treatment waste (GWTW), as an environmentally friendly renewable nanomaterial, was implemented for the removal of anodized aluminum dye Sanodure Green (SG) from aqueous solutions. The capability of the SG metal complex dye removal was assessed by measuring solution decoloration and chromium elimination degree. GWTW was characterized using FTIR, SEM, EDX, TEM, XPS and surface area measurements. Kinetic curves were obtained by changing initial dye concentration, pH, temperature and adsorbent dose. Kinetic studies showed that up to 90 % of SG dye was removed within a contact time of 20 min. The adsorption of the dye was favourable at 293 K temperature in the acidic pH region (pH 1.5–2.0) with maximum adsorption capacity 185 mg g −1 . Langmuir-Freundlich isotherm model as well as hyperbolic tangent, diffusion-chemisorption and Elovich kinetic models accurately describe the dye removal process. The calculated thermodynamic parameters confirmed that SG dye removal occurred spontaneously and exothermically. The magnitude of enthalpy change (ΔH ° = −35.80 kJ mol −1 ) was in agreement with the electrostatic interaction. The adsorption potential of GWTW for SG dye removal was also evaluated using a real wastewater produced after dyeing of anodized aluminum.

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Section: Resultssupporting

confidence: 79%

Section: Resultsmentioning

confidence: 99%

Sustainable removal of anodized aluminum dye by groundwater treatment waste: experimental and modeling

Sodaitienė

Gefenienė

Kaušpėdienė

et al. 2021

Heliyon

View full text Add to dashboard Cite

show abstract

“…The combined contamination of groundwater by heavy metals and organics has become a serious problem worldwide, threatening both the natural ecosystem and human health [1]. Vanadium, a redox-sensitive metal, widely occurring in the Earth's crust, is employed in metallurgy, manufacturing, and petroleum refining industries [2], and is an efficient catalyst in the selective catalytic reduction of nitrogen oxides in exhaust gases [3]. Dissolution of vanadium-rich rocks and anthropogenic activities lead to the presence of vanadium in groundwater [4,5].…”

Section: Introductionmentioning

confidence: 99%

Insights into interactions between vanadium (V) bio-reduction and pentachlorophenol dechlorination in synthetic groundwater

Zhang

Cheng

Shi

et al. 2019

Chemical Engineering Journal

114

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Aquifer co-contamination by vanadium (V) and pentachlorophenol (PCP) involves complicated biogeochemical processes that remain poorly understood, particularly from the perspective of microbial metabolism. Batch experiment results demonstrated that V(V) and PCP could be competitively bio-reduced, with 96.0 ± 1.8% of V(V) and 43.4 ± 4.6% of PCP removed during 7 d operation. V(V) was bio-transformed to vanadium (IV), which could precipitate naturally under circumneutral conditions, facilitating the removal of up to 78.2 ± 3.1% dissolved total V. The PCP reductive dechlorination products were mainly 2,4,6-trichlorophenol and 4-monochlorophenol with lower toxicity. High-throughput 16S rRNA gene sequencing indicated that Pseudomonas, Soehngenia, and Anaerolinea might be responsible for the two bio-transformations, with detected functional genes of nirS and cprA. Extracellular reduction by cytochrome c and intracellular conversion by nicotinamide adenine dinucleotide (NADH) occurred for both V(V) and PCP. Extracellular proteins in microbial-secreted extracellular polymeric substances (EPS) might also be involved in these enzymatic bioprocesses. EPS could protect microbial cells through V(V) binding by the chemically reactive carboxyl (COO-), and hydroxyl (-OH) groups. These findings elucidate the metabolic processes during anaerobic V(V) and PCP biotransformation, advance understanding of their biogeochemical fates, and provide a foundation on which to develop novel strategies for remediation of co-contaminated aquifers.

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“…The raising background pattern of the diffractogram indicates the presence of a large number of substances, probably iron compounds, with a low degree of structure order. Other research also confirmed that iron compounds exist mainly in amorphous forms [13,35,36].…”

Section: Resultsmentioning

confidence: 65%

The properties of sludge formed as a result of coagulation of backwash water from filters removing iron and manganese from groundwater

et al. 2019

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The standard groundwater treatment technology is a simple, non-chemical reagent technology based on aeration and filtration processes. This treatment technology is resulted in the formation of groundwater treatment sludge (GWTS). Because one of the elements of sustainable development is the possibility of their reuse, that water treatment plant operators are looking for new ways of managing these sludges. At present, not all factors determining the adsorptive capacity of water treatment sludge are known. The explanation why the adsorption capacity of sludge with a similar structure and chemical composition may differ significantly will allow for their wider use as adsorbents. The information which must be known to ensure proper sludge management are the quality, chemical composition and texture characteristics of the GWTS. The sludges were characterized by X-ray diffraction, X-ray fluorescence, Fourier transform infrared spectroscopy and N 2 adsorption/desorption isotherms. The results showed that the composition and properties of the GWTS depend primarily on the quality parameters of the raw water and the processes and reagents used in its treatment technology. GWTS contains mainly amorphous iron oxides. Sludges are characterized by a large specific surface area (145 m 2 /g). Due to composition and textural parameters, GWTS demonstrates good adsorption properties toward different compounds such as heavy metals and metalloids. In this article, the authors describe the relationship between properties of resulting sludge and the properties of groundwater, the treatment technology and backwash water treatment from rapid filters.

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Utilization of ferric groundwater treatment residuals for inorganic-organic hybrid biosorbent preparation and its use for vanadium removal

Abstract: Utilization of ferric groundwater treatment residuals for inorganic-organic hybrid biosorbent preparation and its use for vanadium removal, Chemical

Cited by 53 publications

References 52 publications

Sustainable removal of anodized aluminum dye by groundwater treatment waste: experimental and modeling

Sustainable removal of anodized aluminum dye by groundwater treatment waste: experimental and modeling

Insights into interactions between vanadium (V) bio-reduction and pentachlorophenol dechlorination in synthetic groundwater

The properties of sludge formed as a result of coagulation of backwash water from filters removing iron and manganese from groundwater

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