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AbstractAbsolute cross sections for the K-shell photoionization of Be-like boron ions were measured with the ion-photon merged-beams technique at the Advanced Light Source synchrotron radiation facility. High-resolution spectroscopy with E/ E up to 8800 ( E ∼ 22 meV) covered the energy ranges 193.7-194.7 eV and 209-215 eV. Lifetimes of the strongest resonances are determined with relative uncertainties down to approximately 4% for the broadest resonance. The measured resonance strengths are consistent with 60% 1s 2 2s 2 1 S ground-state and 40% 1s 2 2s2p 3 P o metastable-state ions in the primary ion beam and confirmed by comparison with independent absolute photo-recombination heavy-ion storage-ring measurements with B 2+ ions using the principle of detailed balance. Experimental determination of the line width for the 1s2s 2 2p 1 P o resonance gives a value of 47 ± 2 meV and compares favourably to a theoretical estimate of 47 meV from the R-matrix with pseudo-states (RMPS) method. The measured line widths of the 1s2s2p 2 3 P, 3 D resonances are 10.0 ± 2 meV and 32 ± 3 meV, respectively, compared to RMPS theoretical estimates of 9 meV and 34 meV.