Vanadium properties, toxicity, mineral sources and extraction methods: a review

Peng, Hao; Guo, Jing; Li, Bing; Huang, Huisheng

doi:10.1007/s10311-021-01380-y

Cited by 28 publications

(13 citation statements)

References 190 publications

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“…Anionic resins react with and separate pentavalent vanadate ions “V( v )” from other impurities in aqueous solutions, but chelating resins are used to extract V( iv ) from acidic solutions. 80,88 Although there are several papers on using ion exchange resins for the separation of vanadium ions from other impurities in various media, the literature on the extraction of vanadium from fly ash leachate is limited. However, ion exchange technology is primarily applied on the experimental scale and is rarely applied in the industry.…”

Section: Recovery Of V and Ni From The Leaching Solutionsmentioning

confidence: 99%

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Recovery of vanadium and nickel from heavy oil fly ash (HOFA): a critical review

et al. 2023

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Section: Recovery Of V and Ni From The Leaching Solutionsmentioning

confidence: 99%

“…However, ion exchange technology is primarily applied on the experimental scale and is rarely applied in the industry. 88 …”

Section: Recovery Of V and Ni From The Leaching Solutionsmentioning

confidence: 99%

Recovery of vanadium and nickel from heavy oil fly ash (HOFA): a critical review

et al. 2023

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“…Vanadium is an important strategic metal with a vast range of applications in the metallurgical industry, chemical industry, battery, medicine, and other fields. − Currently, vanadium slag is the main direct raw material for vanadium extraction, which is the vanadium-containing tailings in the titanomagnetite steelmaking process. − The typical commercial process of vanadium recovery from vanadium slag involves sodium roasting–water leaching, the principle of which is to convert the insoluble spinel (FeV 2 O 4 , V 3+ ) in vanadium slag into soluble sodium metavanadate (NaVO 3 , V 5+ ) via full oxidation roasting; then it can be leached by water. − The leaching solution requires further purification and precipitation to prepare vanadium oxide (V 2 O 5 ) as the final product. , …”

Section: Introductionmentioning

confidence: 99%

Tuning the Nucleation Rates for High-Efficiency Hydrolysis of Sodium Vanadate Solution

Wang,

Chen,

Qin

et al. 2023

Ind. Eng. Chem. Res.

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Compared to the traditional ammonia salt method, hydrolysis for the precipitation of vanadium is a clean method that does not produce ammonia-bearing wastewater. In this study, a novel strategy of speedy acidification of static sodium vanadate (NaVO3) solution and vanadium slag leaching solution for vanadium hydrolysis was proposed to achieve high-efficiency hydrolysis by tuning the nucleation rates. The results of the parameter experiments showed that NaVO3 solution could be rapidly nucleated within 10 s and completely hydrolyzed in 30 min at a higher pH value of 2.4 and a lower temperature of 80 °C, reaching the precipitation efficiency as high as 99%. Compared to the conventional hydrolysis method, the new method could shorten the reaction time, decrease the dosage of acid, and save energy. The hydrolysis mechanism was studied by in situ focused-beam reflectance measurement and particle video microscopy, indicating that a great amount of reactant was produced because of rapid reaction when H2SO4 was all poured into the static solution. Subsequently, local high supersaturation of the reactant led to the formation of its autogenous crystal seed which resulted in red cake precipitation. In this way, the induced nucleation time of hydrolysis was shortened thereby hydrolysis and vanadium precipitation were promoted. The operation process was simple, and acid consumption, reaction time, reaction temperature, and production cost were effectively reduced, realizing high-efficiency vanadium precipitation. Finally, the kinetics of the hydrolysis process was investigated, and the chemical reaction was the rate-determining step and the apparent activation energy was found to be 50.96 kJ/mol.

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“…Therefore, it is of great scientific and practical significance to prospectively study the removal of vanadium ions, especially V(IV) ions in some acid specific places, such as acid leaching solution of catalytic process, electrolyte of vanadium redox battery, and vanadium recovery acid leaching solution in steel factories. [24,30,31] This is the fundamental guarantee for the sustainable development of vanadium-containing materials research and industry. Herein, we investigated the adsorption behaviors of V(IV) ions on GO in aqueous solution at a low pH value of 2.5 to evaluate the application of GO in V(IV) removal.…”

Section: Introductionmentioning

confidence: 99%

“…The mass production and wide applications of vanadium inevitably lead to a large release of vanadium and severe environmental pollution. Therefore, it is of great scientific and practical significance to prospectively study the removal of vanadium ions, especially V(IV) ions in some acid specific places, such as acid leaching solution of catalytic process, electrolyte of vanadium redox battery, and vanadium recovery acid leaching solution in steel factories [24,30,31] . This is the fundamental guarantee for the sustainable development of vanadium‐containing materials research and industry.…”

Section: Introductionmentioning

confidence: 99%

Removal of Vanadium(IV) Ions from Aqueous Solution by Graphene Oxide

et al. 2022

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Vanadium is a long-confined contaminant. In this study, graphene oxide (GO) was synthesized by the modified Hummers' method and used to remove vanadium(IV). The adsorption isotherms and kinetics of vanadium(IV) on GO at pH 2.5 and three temperatures are measured in batch experiments. The influences of ionic strength is investigated and the regeneration of GO is evaluated by washing with HCl. The results show that the adsorption isotherm corresponds to Temkin model with an adsorption capacity of 70.56 mg/g at 298 K, while the kinetic process coincides with pseudo-secondorder model and approaches to equilibrium in 6 h. The adsorption capacity of GO is not influenced by Na + ionic strength, but sharply inhibited by Ca 2 + . The superior adsorption is dominated by electrostatic interaction, coordination bonding, and hydrogen bonding. Moreover, the GO is reusable, as shown by maintaining 53.4 % of the initial efficacy after five sequential adsorption-desorption cycles.

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Vanadium properties, toxicity, mineral sources and extraction methods: a review

Cited by 28 publications

References 190 publications

Recovery of vanadium and nickel from heavy oil fly ash (HOFA): a critical review

Recovery of vanadium and nickel from heavy oil fly ash (HOFA): a critical review

Tuning the Nucleation Rates for High-Efficiency Hydrolysis of Sodium Vanadate Solution

Removal of Vanadium(IV) Ions from Aqueous Solution by Graphene Oxide

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