The effect of deposition temperature on the properties of 355-nm high-reflectivity ͑HR͒ coatings was investigated. A series of 355-nm HR coatings were deposited by electron-beam evaporation using the same deposition process, but different deposition temperatures: 200, 250, 280, and 320°C. Transmittance and high reflectance of the samples were measured with a Lambda 900 spectrometer, and the highest reflectance, 98.7%, was achieved at a deposition temperature of 280°C. The laser-induced damage threshold ͑LIDT͒ was measured with a 355-nm pulsed laser with a pulse width of 8 ns. It was found that the deposition temperature had a significant effect on the LIDT of coatings. LIDTs up to 18.5 J / cm 2 were achieved when the deposition temperature was 280°C. The LIDT of the coating deposited at 280°C is about three times greater than that of coatings deposited at the other temperatures. Damage morphologies of samples at different deposition temperatures were observed with a Leica-DMRXE microscope. Microstructures of the samples were characterized by x-ray diffraction ͑XRD͒. An absorptancedominated model is proposed, which agrees very well with the damage threshold results.