Introduction: Water quality surveillance is the main strategy to ensure its potability and to assess the risks that water supply systems and alternative solutions may pose to human health. Among the surveillance parameters, fluorine ion (fluorides) stands out, due to the risks and benefits that its concentration may represent for human health. Objective: Analyze the structure and degree of implementation of public water quality monitoring activities in relation to the fluoride parameter between Brazilian states, including the Federal District. Methods: Twenty-seven questionnaires were applied to the authorities responsible for water surveillance in order to investigate the monitoring activities of the water quality for human consumption. The level of implementation was considered incipient, intermediate or advanced according to criteria/ indicators defined based on a logical model. Results: Only seven federative units were monitoring the fluoride parameter while the others units needed better structuring, implementation of activities, encouragement and/or interaction between government levels, administrative cores and experts. Conclusion: To achieve an advanced grade of implementation of the fluoride surveillance in all units of the federation, coordination mechanisms and the governance process of this policy in this institutional subsector of the health sector should be improved.