“…For nonperiodic or heterogeneous porous media, where REV selection Previous studies have suggested that colloid transport in porous media is significantly affected by particle size [Fontes et al, 1991, Gannon et al, 1991. Early breakthrough of colloids and biocolloids as compared to that of conservative tracers has been observed in several studies [Bales et al, 1989;Toran and Palumbo, 1992;Powelson et al, 1993;Grindrod et al, 1996;Dong et al, 2002;Keller et al, 2004;Vasiliadou and Chrysikopoulos, 2011;Sinton et al, 2012;Syngouna and Chrysikopoulos, 2013;Chrysikopoulos and Syngouna, 2014]. Colloid early breakthrough can be attributed to effective porosity reduction (colloids cannot penetrate smaller pores due to their inability to fit into them), preferential flow paths through high-conductivity regions, and exclusion from the lower-velocity regions [Chrysikopoulos and Abdel-Salam, 1997;Dong et al, 2002;Ginn, 2002;Ahfir et al, 2009], which can also be viewed as a reduction of the effective porosity of the porous medium [Morley et al, 1998].…”