Viscosité des mélanges binaires de nitrates fondu en fonction de rayon ionique

Murgulescu, I. G.; Zuca, S.

doi:10.1016/0013-4686(66)87035-4

Cited by 22 publications

(25 citation statements)

References 3 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…5 for the former system at 573 and 623 K, and in Fig. 6 for the latter at 543 and 643 K. The equivalent conductivities are calculated from the available data on specific conductivities ((Li-Rb) N03 [20] and (Li-Cs) N03 [22]) and densities [23]. …”

Section: Resultsmentioning

confidence: 99%

“…The internal mobilities of Li + at 623 K in the nitrate mixtures so far studied are plotted against the molar volume in Figure 7. The internal mobility in the system (Li-K)N03 is evaluated from the data on the external mobility ratio [9], the specific conductivity [27,28] and the density [23]. That in the system (Li-T1)N03 is recalculated from the equivalent conductivity data given by Brillant [29].…”

Section: Discussionmentioning

confidence: 99%

See 1 more Smart Citation

Internal Cation Mobilities in the Molten Systems (Li-Rb)N0 3 and (Li-Cs)NO s

Okada

Takagi

Kawamura

1979

Zeitschrift Für Naturforschung A

View full text Add to dashboard Cite

The relative differences in internal cation mobilities are measured for the molten systems (Li-Rb)N03 and (Li-Cs)N03 over a wide range of temperatures and concentrations with a countercurrent electromigration method, and the internal mobilities are calculated from these results and the available data on the electrical conductivity.The following phenomena are observed: (a) under some conditions the electrical mobility of Li+ is lower than that of the larger cation, (b) at a given temperature the mobility of Li+ decreases with increasing molar volume of the mixture, and (c) at low temperatures the isotherms of the mobility of the large cation show a maximum at some low concentration of that ion. These phenomena are interpreted in terms of the free space and the pair potential between cation and anion.

show abstract

Section: Resultsmentioning

confidence: 99%

Section: Discussionmentioning

confidence: 99%

Internal Cation Mobilities in the Molten Systems (Li-Rb)N0 3 and (Li-Cs)NO s

Okada

Takagi

Kawamura

1979

Zeitschrift Für Naturforschung A

View full text Add to dashboard Cite

show abstract

“…The values of A were obtained from the available data on electrolytic conductivities of (I) [12] and (II) [13] and on densities [14]. The isotherms of b x and b2 are shown for (I) at 573 and 653 K in Fig.…”

Section: Resultsmentioning

confidence: 99%

Internal Cation Mobilities in the Molten Systems (Li-Na)NO₃ and (Na-Cs)NO₃

Yang

Takagi

Okada

1980

Zeitschrift Für Naturforschung A

View full text Add to dashboard Cite

For the molten salt systems (Li-Na)N03 and (Na-Cs)N03, relative differences of intei'nal mobilities have been measured with the Klemm method. The internal mobilities, b, are calculated from these data and the available conductivity data. In the mixtures of the former system, &xa is always greater thanIn the latter system, the Chemla crossing point occurs. It is found that bu and &xa in the binary alkali nitrate systems so far investigated are well expressed, except at small molar volumes, by b = {^4/(F-F 0 )} exp(-E/RT) with constant A and E, where V is the molar volume and F° a constant for bu and nearly a constant for The values of bes at equal concentrations of CSNO3 in the systems (Li-Cs)N03 and (Na-Cs)NOs are practically equal. The internal mobilities obtained are discussed in terms of free space, mutual ionic attraction and thermal agitation.

show abstract

“…The electrical conductivity of NaBr was found in excellent agreement with the reference value [12] critically evaluated by Janz [13] from several experimental sources [12,[14][15][16][17]. At 1050 K, both values agree within 0.3%.…”

Section: Electrical Conductivitymentioning

confidence: 60%