2005
DOI: 10.1021/je050288d
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Viscosity Measurements on Water Vapor and Their Evaluation

Abstract: Results of new high-precision measurements of the viscosity of water vapor at low densities are reported. The measurements were performed using an all-quartz oscillating-disk viscometer with small gaps. Ten isochoric series were carried out at temperatures between (298 and 438) K and at densities from (0.001 to 0.013) mol‚L -1 . The uncertainty is estimated to be ( 0.2 % at ambient temperature increasing up to ( 0.3 % at higher temperatures. Isothermal values were analyzed with a density series for the viscosi… Show more

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Cited by 34 publications
(41 citation statements)
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“…Our H 2 O profiles agree less, and our OH slopes, the least, due mainly to the strong effect that neutral collisions have on those more polar molecules. In particular, C10 used a much larger cross section for neutral collisions involving H 2 O and OH [Teske et al, 2005] than for atomic oxygen [Bondi, 1964]. This helps to further explain our agreement with their oxygen profile since we exclude neutral-neutral collisions from our model altogether.…”
Section: Discussionmentioning
confidence: 99%
“…Our H 2 O profiles agree less, and our OH slopes, the least, due mainly to the strong effect that neutral collisions have on those more polar molecules. In particular, C10 used a much larger cross section for neutral collisions involving H 2 O and OH [Teske et al, 2005] than for atomic oxygen [Bondi, 1964]. This helps to further explain our agreement with their oxygen profile since we exclude neutral-neutral collisions from our model altogether.…”
Section: Discussionmentioning
confidence: 99%
“…To the database, we added several data sets [30][31][32][33][34][35][36] published after the compilation of Ref. 29.…”
Section: Experimental Datamentioning
confidence: 99%
“…which for water at 180 K gives σ 54Å 2 . For a more accurate value, appropriate for use in our calculations involving viscous spreading, we employ the results of Teske et al (2005), who measured experimentally the viscosity of water vapor at temperatures 300-450K and a range of densities. We use the standard relation for kinematic viscosity ν,…”
Section: Processmentioning
confidence: 99%