Fundamental details of the spatial and/or temporal evolution of in‐cylinder processes of internal combustion engines may be gained from various optical diagnostics. Application of optical diagnostics requires experimental facilities with optical access, appropriate light detection instrumentation, and potentially external light sources and delivery optics. Three types of optical facilities that recreate engine‐relevant high pressure, high temperature conditions are reviewed here: engines, rapid compression machines, and pressurized high temperature spray or premixed fuel–air chambers. In addition, several of the more commonly applied optical diagnostic techniques that can detect combustion‐generated light emission, attenuation and scattering of light from external sources, and artificially generated emission, including laser‐induced processes, are also briefly reviewed.