With the significant rise of low power embedded devices in various applications of both consumer and commercial usage, the surge for continuous power requirements has initiated promising research toward alternative sources of energy. It includes the domain of wireless power transmission, internet‐of‐things, wireless sensor nodes, machine‐to‐machine, and radio frequency identification. Thus, the overall scope of this review article is to witness microwave antennas and its implementation in RF energy harvesting system through ambient RF signals. For this reason, unified understanding of classical electromagnetism is needed; beginning with the fundamentals of RF transmission and the exploration of concepts such as Fraunhofer's Distance and Friis Transmission Equation. It is followed up by the analogy of dependency of parameters like circuit build‐up, conversion efficiencies and amount of power harvested, which is quite crucial from the rectifier point‐of‐view. For better improvisement in RF energy harvesting systems, five different cases of monopole antennas are explored with reflector surfaces such as PEC (perfect electrical conductor) and AMC (artificial magnetic conductor) integrated with the rectifier circuit. Implementation with wide diversity has proposed a generalized solution for achieving tradeoffs: polarization and pattern diversity with consistent system efficiency; leads to clean and sustainable energy for low power‐embedded devices.