2010
DOI: 10.1016/j.saa.2009.12.061
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Voltammetric and spectroscopic investigations of 4-nitrophenylferrocene interacting with DNA

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Cited by 85 publications
(46 citation statements)
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“…The diffusion-control behavior was evident from the linear plot of the voltammetric response as a function of ν 1/2 . From the slope of the obtained line, diffusion coefficient for free AZT (D f ) was calculated as 5.86× 10 -5 cm 2 s -1 , whereas for the AZT-DNA complex, D b was reduced to 2.90 × 10 -5 cm 2 s -1 .The negative shift in potential of C 1 during successive additions of DNA, confirms the nonintercalative nature of the interaction, indeed it refers to electrostatic interactions with DNA[21,[25][26][27][28].…”
mentioning
confidence: 74%
“…The diffusion-control behavior was evident from the linear plot of the voltammetric response as a function of ν 1/2 . From the slope of the obtained line, diffusion coefficient for free AZT (D f ) was calculated as 5.86× 10 -5 cm 2 s -1 , whereas for the AZT-DNA complex, D b was reduced to 2.90 × 10 -5 cm 2 s -1 .The negative shift in potential of C 1 during successive additions of DNA, confirms the nonintercalative nature of the interaction, indeed it refers to electrostatic interactions with DNA[21,[25][26][27][28].…”
mentioning
confidence: 74%
“…A c c e p t e d M a n u s c r i p t 16 the binding constants and the number of binding sites [67,68]. Fluorescence intensity of a probe can be quenched by various molecular interactions, viz., excited-state reactions, molecular rearrangements, energy transfer, ground state complex formation and collisional quenching [69].…”
Section: Page 18 Of 25mentioning
confidence: 99%
“…As shown in Figure 8, our observations demonstrate that the relevant peak potentials of TTF-(COONBu 4 ) 2 positively shift upon addition of P-gp, with accompanying considerable decrease in relevant peak currents. Based on the decrease in peak currents of TTF-(COONBu 4 ) 2 upon addition of P-gp, the apparent binding constants are calculated according to the following equation [31,32]:…”
Section: Electrochemical Detection Recognition Of Mdr Leukemia Cells mentioning
confidence: 99%