Voltammetric Membrane Electrodes. I. Basic Theory and Characteristics of Thallous and Cadmium Reduction

Temporal characterization of perfluorinated ion exchange coated microvoltammetric electrodes for in vivo use

“…Under these conditions, the concentration gradient is affected by electrolysis as well as permeation (18,24,25). Although this can be accounted for mathematically (39)(40)(41)(42)(43), electrochemical generation of the redox partner, Ru(bpy)33+, alters the permeation time as observed in our amperometric experiments. In fact, a difference in the permeation time between the first and second exposure to Ru(bpy)33+ is indication of charge transport via intermolecular electron exchange.…”

Catalytic and Kinetic Waves in Polarography

“…To study the inhibiting effect of the layer when the thickness and the properties of the layer remain constant with time and also remain constant if the electrode potential and the composition of the solution changes, Fischer [423] used an electrode covered with a cellophane membrane in chronopotentiometric investigations of different electrode processes. This cellophane membrane formed a "homogeneous" medium of known thickness [424]. The inhibiting effect under these conditions apparently has a different nature from that encountered in investigations by Loshkarev and Kryukova, in which the inhibiting layer had molecular dimensions.…”

Automatic simulation of electrochemical transients assuming finite diffusion space at planar interfaces, by the adaptive Huber method for Volterra integral equations

“…[48,49]). The current is proportional to K P j ðtÞ when the boundary at x = L is impermeable, or to K I j ðtÞ when the boundary is permeable (the assignment of the functions is reverse than in the case of the kernels).…”