“…The LOD was calculated using the following equation, LOD = 3 S/M where, S is the standard deviation and M is the slope (sensitivity) obtained from the calibration curves [45].…”
Section: Simultaneous Determination Of Da and Ua By Cyclic Voltammetrymentioning
“…The LOD was calculated using the following equation, LOD = 3 S/M where, S is the standard deviation and M is the slope (sensitivity) obtained from the calibration curves [45].…”
Section: Simultaneous Determination Of Da and Ua By Cyclic Voltammetrymentioning
“…The -SO 3 H group of poly (brilliant blue) could dissociate favorably into a negatively charged SO 3 -group under this condition the -NH 2 group of DA could obtain a proton and form the positive ion of DA. Therefore the negative charge -SO 3 -on the surface of poly (brilliant blue) MCPE has a well affinity to the DA positive ions and could catalyse and promote the oxidation of DA [32][33][34].…”
Section: Electrochemical Characterization Of Poly (Brilliant Blue) MCmentioning
Poly (brilliant blue) modified carbon paste electrode was fabricated for the detection of dopamine in the presence of large excess of ascorbic acid and uric acid in phosphate buffer solution of pH 7.4. The redox peaks obtained at poly (brilliant blue) modified carbon paste electrode shows good electrocatalytic activity towards the oxidation of dopamine. From the study of scan rate variation the electrode process was found to be adsorption controlled. The limit of detection of dopamine was found to be 6.7 × 10 -7 M. and the simultaneous study shows the good result with peak to peak separation between dopamine and other two analytes ascorbic acid and uric acid by both cyclic voltammetry and differential pulse voltammetric techniques.
“…The scan rate varying study showed that current improved linearly with the square root of scan rate range of 50 to 400 mVs -1 The graph of anodic peak current (Ipa) versus the square root of scan rate showed a linear relationship of Ipa and scan rate. The correlation coefficient was found to be 0.9950 Figure 3b it indicates that the electrode process was diffusion controlled [32][33][34][35]. The difference between the anodic and cathodic peak potential (Δ Ep) increasing with increasing the scan rate [36][37][38].…”
Section: Cyclic Voltammetric Studies Of Da At Cyclosporine Mcpementioning
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