Volumetric Behavior of Carbon Dioxide + Butan-1-ol Mixtures at 313.15 K

Abstract

Volumetric behavior was measured of carbon dioxide + butan-1-ol mixtures at 313.15 K using a vibrating tube density meter. The saturated pressures were also measured of carbon dioxide + butan-1-ol mixtures at 313.15 K by the conventional synthetic method. The equilibrium vapor compositions were newly evaluated by combining the molar volume equation, the experimental values of the equilibrium vapor density, vapor density of pure carbon dioxide, and pressure.

Compressed Liquid Densities of Binary Mixtures of 1-Butanol and Diethylene Glycol Dimethyl Ether from (283 to 363) K at Pressures up to 100 MPa

“…The absolute deviations of Wong and Hayduk 21 are within 0.3% at 298.2 and 323.2 K and up to around 0.7% at 348.2 K. For data measured by Ulbig et al, 24 the percentage deviations are scatterly distributed below the zero line and the maximum absolute deviation is 0.31%. For the other data sets measured with vibrating-tube densimeter, 25,26,[31][32][33]37,38 the percentage deviations are within ±0.25%.…”

“…Relative deviations between published density data at elevated pressures and the equation of this work for 1-butanol (data taken from refs , , , and − and from this work).…”

“…In this work, to the best of our knowledge, we surveyed the experimental density measurements of 1-butanol in the literature. Table summarizes the density of 1-butanol performed at high pressure, detailing the methods and temperature and pressure ranges. − A full revision of literature data of the density data of 1-butanol can also be found in Safarov et al The published experimental data before 1994 were reviewed and critically evaluated by Cibulka and Zikova with a Tait equation. Besides, Alaoui et al presented a good comparison with the equation proposed by Cibulka and Zikova .…”