2016
DOI: 10.1007/s10967-016-4869-3
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Wastewater treatment with ionizing radiation

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Cited by 49 publications
(14 citation statements)
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“…This competition can affect the efficiency of the purification process [14], these substances are called • OH radical scavengers as they usually cause a decrease in the degradation efficiency [15,16]. Wojnarovits and Takacs [17] showed that the pH value of a radiationtreated solution has a significant effect on the progress of competitive reactions with hydroxyl radicals. The reaction with chloride ions is predominant at pH < 5, while the reaction with carbonate and bicarbonate ions is predominant at a neutral or slightly Water and wastewater subjected to purification and treatment processes are very complex matrices.…”
Section: 𝑒 + 𝐻 → 𝐻 •mentioning
confidence: 99%
“…This competition can affect the efficiency of the purification process [14], these substances are called • OH radical scavengers as they usually cause a decrease in the degradation efficiency [15,16]. Wojnarovits and Takacs [17] showed that the pH value of a radiationtreated solution has a significant effect on the progress of competitive reactions with hydroxyl radicals. The reaction with chloride ions is predominant at pH < 5, while the reaction with carbonate and bicarbonate ions is predominant at a neutral or slightly Water and wastewater subjected to purification and treatment processes are very complex matrices.…”
Section: 𝑒 + 𝐻 → 𝐻 •mentioning
confidence: 99%
“…The amount of the specific radicals available for interaction with certain solute could be calculated using the reaction probability (P A ) according to the following equation: Figure 2 illustrates the reactions between the primary intermediates and the available anions in the wastewater effluents. Wojnarovits and Takacs [30] indicated that intermediate reaction with chloride ions is dominant at pH < 5, whereas the reaction with carbonate and bicarbonate ions are dominant at neutral or slightly alkaline pH. The produced free radicals will subsequently react with dissolved organic matters in the wastewater via direct electron transfer (outer sphere electron), addition to double bonds (inner sphere electron) or abstraction of H-atoms from C-H bonds.…”
Section: Decomposition and Removal Mechanismsmentioning
confidence: 99%
“…Most principal reactions of reactive products of water radiolysis with a solute, concerning wastewater treatment by ionizing radiation, have been overviewed recently [5]. …”
Section: Industrial Wastewatermentioning
confidence: 99%
“…However, the attribution of radiation treatment to AOPs seems to be not quite correct, since ionizing radiation initiates in irradiated media not only oxidizing processes but also reducing ones. Though the formation of reducing particles under radiolysis, as well as under photolysis, sonolysis, electrolysis, and so on, has been mentioned earlier repeatedly [3][4][5], the role of reductive processes in the purification of water and wastewater was not considered as specific and important one, partly due to comparatively low importance of the processes in the decomposition of organic compounds.…”
Section: Introductionmentioning
confidence: 99%