2007
DOI: 10.1002/macp.200600654
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Water‐Based Polyurethane Filled with Multi‐Walled Carbon Nanotubes Prepared by a Colloidal‐Physics Method▪Author: This manuscript has been thoroughly edited. Please read the proofs carefully to ensure that no unintentional shift in meaning has been introduced.▪

Abstract: MWCNT/water‐based PU composites were synthesized by means of a colloidal‐physics method. The effect of MWCNT addition on the electrical and thermal properties of the composites and the effect of NaCl addition on film formation of the PU latexes were investigated. The electrical conductivity of the water‐based PU was improved by more than four orders of magnitude, but remained still four orders of magnitude lower than that of the MWCNTs. The percolation threshold was found to be at 0.5 wt.‐% MWCNT. The thermal … Show more

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Cited by 34 publications
(7 citation statements)
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“…Polyurethane (PU) is a flexible and elastic polymer synthesized by the reaction of diisocyanates with diols and widely used in coatings, adhesives, sealants, thermoplastic elastomers, and medical devices . Nanotechnology is considered as a new approach to developing next‐generation PU materials for broader industrial applications, with nanomaterials showing a strong ability to comprehensively upgrade the physical properties of PU materials for improved thermal, mechanical, and electrical properties of nanocomposites . Graphene, a one‐atom‐thick two‐dimensional basal plane of graphite, has attracted considerable attention because of its high mechanical properties (∼1000 GPa), electrical conductivity (∼6000 S cm −1 ), thermal conductivity (∼5000 W m −1 K −1 ), surface area (2630 m 2 g −1 ), and gas impermeability .…”
Section: Introductionmentioning
confidence: 99%
“…Polyurethane (PU) is a flexible and elastic polymer synthesized by the reaction of diisocyanates with diols and widely used in coatings, adhesives, sealants, thermoplastic elastomers, and medical devices . Nanotechnology is considered as a new approach to developing next‐generation PU materials for broader industrial applications, with nanomaterials showing a strong ability to comprehensively upgrade the physical properties of PU materials for improved thermal, mechanical, and electrical properties of nanocomposites . Graphene, a one‐atom‐thick two‐dimensional basal plane of graphite, has attracted considerable attention because of its high mechanical properties (∼1000 GPa), electrical conductivity (∼6000 S cm −1 ), thermal conductivity (∼5000 W m −1 K −1 ), surface area (2630 m 2 g −1 ), and gas impermeability .…”
Section: Introductionmentioning
confidence: 99%
“…The nanolatex control film has an isotropic thermal diffusivity α = 0.085 mm 2 /s. The corresponding thermal conductivity k = αρ C p = 0.144 W/m/K (ρ = 1.19 g/cm 3 ; C p = 1.425 J/g/K) is typical of many polymers and latex films ,, .…”
mentioning
confidence: 99%
“…For example, negative charges were incorporated onto CNTs via sodium dodecyl sulphate (SDS) to achieve a water‐based PU/CNTs colloidal dispersion and resulting conductive composite. [ 94 ] PEDOT:PSS with negative charges can be blended with water‐based PU to obtain strain responsive composites. [ 95 ] Since the opposite charged polymers would lead to the aggregation, positively charged polymers are usually incorporated into negatively charged water‐based PU through layer‐by‐layer assembly, not direct mixing.…”
Section: Flexible and Stretchable Electronicsmentioning
confidence: 99%