Proton
exchange membrane (PEM) fuel cells, which can directly convert
chemical energy to electricity, are promising as the next-generation
energy harvesting method. Among all of the components, the microporous
layer (MPL) controls the water and gas transport between the gas diffusion
layer and the catalysis layer, where carbon black is one of the traditional
materials for fabrication. However, owing to its energy-intensive
preparation method, high capitalized cost, and low water transport
rate features, the realization of carbon black on a large scale still
faces obstacles. Here, we demonstrate a combination of three carbon
materials for synthesizing the MPL using carbon black (CB), coaly
graphite (CG), and graphene oxide (GO), whose synergistic effect ensures
a high output in PEM fuel cells. CB is partially replaced by CG, which
reduces the carbon and toxic gas footprint while still maintaining
a high power density. This work for designing membrane structures
for the MPL opens opportunities for developing highly efficient PEM
fuel cells.