Experimental techniques have been developed to evaluate performance of nanoemulsions as pre-pad fluid for reducing water-cut in tight gas formations with multistage hydraulic fractures. More specifically, an aminopolysiloxane nanoemulsion was prepared and formulated in the laboratory for effective and efficient water control. The water-control mechanisms of nanoemulsions as pre-pad fluid in hydraulic fracturing were identified by performing the scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), spontaneous imbibition tests, and wettability measurements. The SEM and XPS tests confirm that certain changes occur in the element compositions and microstructure of the core surface before and after introducing the prepared nanoemulsions on the reservoir rock surface. Such changes irreversibly alter its wettability, indicated by the measured contact angle from 75°to 128°. During the displacement experiments, there exists a disproportionate permeability reduction on relative permeability of the gas−water systems. Gas relative permeability has only a small decline by less than 20% at different water saturations, while water relative permeability is reduced up to 60%. In addition, effective gas permeability for the core samples treated with nanoemulsions can be rapidly restored by the potential acid hydrolysis. This leads to not only creating new paths for gas flow in hydraulic fractures or invaded zones but also reducing the inertial resistance of gas flow in porous media by nanoemulsion retention.