Wireless power transfer and backscatter communications have emerged as promising solutions for energizing and communicating with power limited devices. Despite some progress in wirelessly powered backscatter communications, the focus has been concentrated on backscatter and energy harvester. Recently, significant progress has been made on the design of transmit multisine waveform, adaptive to the Channel State Information at the transmitter (CSIT), in point-to-point backscatter system. In this paper, we leverage the work and study the design of transmit multisine waveform in a multiuser backscatter system, made of one transmitter, one reader and multiple tags active simultaneously. We derive an efficient algorithm to optimize the transmit waveform so as to identify the tradeoff between the amount of energy harvested at the tags and the reliability of the communication, measured in terms of Signal-to-Interference-plus-Noise Ratio (SINR) at the reader. Performance with the optimized waveform based on linear and nonlinear energy harvester (EH) models are studied. Numerical results demonstrate the benefits of accounting for the energy harvester nonlinearity, multiuser diversity, frequency diversity and multisine waveform adaptive to the CSIT to enlarge the SINR-energy region.tags can operate with low power as they do not require RF components to generate carrier signal. Although backscatter communications has originally been limited to simple radio frequency identification (RFID) applications, it has received a renewed interests in recent years with advances in backscatter communication theory, including coding [5], beamforming [4], performance analysis of large networks [6], [7].RF transmitter in backscatter communications typically transmit sinusoidal continuous waveform (CW). Significant progress has recently been made on the waveform design in wireless power transfer (WPT), in order to improve the efficiency and DC output power of the energy harvester. In particular, [8] studies the nonlinear behaviour of RF-to-DC converter and suggests that significant DC power gain can be obtained by using multisine waveform with zero phase between the sinewaves. In [9], a multisine waveform transmission has been introduced to extend the reading signal.[10] presented multisine waveform method to improve power sensitivity of the tags and conduct a survey of reading range improvement for several commercial RFID tags. Motivated by the promising gains, a systematic approach towards waveform design for WPT was proposed in [11]. In [11], optimized multisine waveforms, adaptive to the CSIT, have been shown to provide significant gain by exploiting the rectifier nonlinearity and the frequency selectivity of the channel.Backscatter communication can leverage this recent progress in WPT waveform design and depart from the conventional CW transmission. Recently, [12] studies the tradeoff between harvested energy and backscatter communication in point-to-point deployment. It is noted that waveform design for WPT and backscatter communicati...