2022
DOI: 10.1021/acs.inorgchem.2c03094
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Well-Defined and Highly Effective Nickel Catalysts Coordinated on Tridentate SNO Schiff-Base Derivatives for Alternating Copolymerization of Epoxides and Anhydrides

Abstract: A series of Ni complexes supported by SNO Schiff-base derivatives were synthesized in this study. Complex synthesis and characterization data are reported herein. Treatment of the pro-ligands [L 1 -H = 2-(((2-(methylthio)ethyl)imino)methyl)phenol, L 2 -H = 2,4-di-tert-butyl-6-(((2-(methylthio)ethyl)imino)methyl)phenol, L 3 -H = 2-(((2-(methylthio)ethyl)imino)methyl)-4,6-bis(2-phenylpropan-2-yl)phenol, L 4 -H = 4-bromo-2-(((2-(methylthio)ethyl)imino)methyl)phenol, and L 5 -H = 4-chloro-2-(((2-(methylthio)ethyl)… Show more

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Cited by 3 publications
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“…These bond lengths of complexes Ni­(II) and Cu­(II) are all within normal ranges, which is consistent with those previously reported for Ni­(II) and Cu­(II) complexes (Tables S6 and S7). , …”
Section: Resultsmentioning
confidence: 99%
“…These bond lengths of complexes Ni­(II) and Cu­(II) are all within normal ranges, which is consistent with those previously reported for Ni­(II) and Cu­(II) complexes (Tables S6 and S7). , …”
Section: Resultsmentioning
confidence: 99%