What Is a “Clean” Surface?

Lyons, Ernest H.

doi:10.1149/1.3071689

Cited by 1 publication

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“…Furthermore, it affords a starting point for development of the important theory of effect of surface films on electrodeposition (12). Establishment of the metallic bond draws the ion still closer to the metal lattice and the bridging water molecule is expelled.…”

Section: July 195~mentioning

confidence: 99%

“…Although this mechanism is purely hypothetical, it provides a plausible picture of the deposition process, which is needed to explain correlations between electronic structure and electrode behavior. Furthermore, it affords a starting point for development of the important theory of effect of surface films on electrodeposition (12). Obviously the picture is somewhat oversimplified, for it neglects effects of steric factors and of ionic double layers.…”

Section: July 195~mentioning

confidence: 99%

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Electronic Configuration in Electrodeposition from Aqueous Solutions

Lyons

1954

J. Electrochem. Soc.

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It is proposed that electrodeposition proceeds through an intermediate complex ion adsorbed on the cathode by a coordinated bridge. Subsequently, the bridge is eliminated and a metallic bond established. By applying Pauling's theory of the metallic state, reversible deposition of post-transition metals and irreversible deposition of transition metals are explained. A close correlation with electron-transfer reactions is shown. Inclusions in deposits represent residual coordinated groups, in agreement with results of recent studies. ) unless CC License in place (see abstract). ecsdl.org/site/terms_use address. Redistribution subject to ECS terms of use (see 128.187.103.98 Downloaded on 2015-05-19 to IP ) unless CC License in place (see abstract). ecsdl.org/site/terms_use address. Redistribution subject to ECS terms of use (see 128.187.103.98 Downloaded on 2015-05-19 to IP

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Section: July 195~mentioning

confidence: 99%

Section: July 195~mentioning

confidence: 99%