“…10,11 Belonging to the semimetal group, the small overlap between the bottom of the conduction band and the top of the valence band provides interesting physicochemical and catalytic properties to bismuth. [12][13][14][15] For instance, bismuth-based composites gained a signification interest as active materials for the photo-/electrocatalytic synthesis of valuable chemicals (production of hydrogen peroxide, 16 ammonia 17 , formate 18,19 , hydrogen 15,20,21 ), the control of the catalytic selectivity, [22][23][24][25] the sensing, 26 and energy conversion [27][28][29][30] applications.…”