Capacitors
are a ubiquitous component of many modern-day electronics
that provide remote sensing, power conditioning, electrical noise
filtering, signaling coupling or decoupling, and short-term memory
storage. With the desire for flexible, smaller, and more powerful
electronics, capacitors and other electrical components will have
to be improved to meet these growing demands. Carbon-derived materials
are good candidates for use as electrodes in electrochemical capacitors
(i.e., supercapacitors) because of their nanoscale and flexible architecture.
However, implementations of these materials tend to have inferior
specific capacitance and energy density compared with other options.
In this work, different carbon derivatives (graphene oxide, Claisen
graphene, activated charcoal oxide, and activated charcoal Claisen)
were chemically modified via nitrogen doping to optimize the capacitance,
power density, energy density, and the overall electrochemical performance
of the resulting supercapacitors. Devices with a two-electrode configuration
were assembled and confirmed the superior performance for all N-doped
carbon derivatives in all analyzed parameters (specific capacitance,
energy density, and power density) when compared with their undoped
counterparts. The maximum areal capacitance obtained was 421.44 mF/cm2 for the N-doped activated charcoal oxide, which represents
an improvement of 242.2% in comparison with the corresponding nonmodified
sample, in addition to a 153% improvement in the energy density and
strong retention in specific capacitance (in the order of 86% at 1000
cycles of operation).