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For the processing of coal mine methane into hydrogen-containing gas, a catalytic process of methane tri-reforming was studied under long-term testing conditions (800 ᵒC, 100 h). The tests were carried out using the actual composition of the methane-containing mixture recovered by mine drainage systems of the Raspadskaya mine (Kuzbass, Russia). Gas chromatographic analysis of coal mine gas showed that it contains the following components with an average concentration, vol.%: CH4 – 40.18, N2 – 36.30, H2O – 12.90, O2 – 9.77, CO2 – 0.88, C2H6 – 0.25 and C3H8 – 0.04. It was found that the average O/C molar ratio was 0.87, so CO2 addition to the methane-containing mixture was done to maintain the O/C ratio > 1.1 to ensure stable operation (without significant coke formation) during the catalytic process. Long-term catalytic tests have shown high parameters of the methane tri-reforming process, which were stable over the time of operation. At a temperature of 800 ᵒC, after 100 h of process using the Ce0.2Ni0.8O1.2/Al2O3 catalyst, the hydrogen yield was 85% at a methane conversion of 80%. A comparative analysis of the properties of fresh and spent Ce0.2Ni0.8O1.2/Al2O3 catalyst was performed using low-temperature nitrogen adsorption, powder X-ray diffraction, electron microscopy and thermal analysis. It was established that the mesoporous texture of the catalyst was retained, but the dispersion of the active component decreased. The Ce0.2Ni0.8O1.2/Al2O3 catalyst is resistant to thermal sintering and coking, which ensures no deactivation. The use of tri-reforming technology for the utilization of coal mine methane is a step towards “green” coal mining, ensuring sustainable development of society.
For the processing of coal mine methane into hydrogen-containing gas, a catalytic process of methane tri-reforming was studied under long-term testing conditions (800 ᵒC, 100 h). The tests were carried out using the actual composition of the methane-containing mixture recovered by mine drainage systems of the Raspadskaya mine (Kuzbass, Russia). Gas chromatographic analysis of coal mine gas showed that it contains the following components with an average concentration, vol.%: CH4 – 40.18, N2 – 36.30, H2O – 12.90, O2 – 9.77, CO2 – 0.88, C2H6 – 0.25 and C3H8 – 0.04. It was found that the average O/C molar ratio was 0.87, so CO2 addition to the methane-containing mixture was done to maintain the O/C ratio > 1.1 to ensure stable operation (without significant coke formation) during the catalytic process. Long-term catalytic tests have shown high parameters of the methane tri-reforming process, which were stable over the time of operation. At a temperature of 800 ᵒC, after 100 h of process using the Ce0.2Ni0.8O1.2/Al2O3 catalyst, the hydrogen yield was 85% at a methane conversion of 80%. A comparative analysis of the properties of fresh and spent Ce0.2Ni0.8O1.2/Al2O3 catalyst was performed using low-temperature nitrogen adsorption, powder X-ray diffraction, electron microscopy and thermal analysis. It was established that the mesoporous texture of the catalyst was retained, but the dispersion of the active component decreased. The Ce0.2Ni0.8O1.2/Al2O3 catalyst is resistant to thermal sintering and coking, which ensures no deactivation. The use of tri-reforming technology for the utilization of coal mine methane is a step towards “green” coal mining, ensuring sustainable development of society.
Relevance. Victims’ own negligence is a main cause of injuries among the EMERCOM of Russia officers.The objective is to analyze occupational injury scenarios caused by ‘victims’ own negligence’ among the Federal Fire Service (FFS) officers and workers of the EMERCOM of Russia within 2010 to 2021 timespan.Methods. The study examined 10,000 fire service officers to analyze the incidence of occupational injuries due to ‘victims’ own negligence within 2010 to 2021, depending on the injury-associated activity, patient’s position, age, type of injury, weekday and month of injury. We calculated arithmetic average values and errors (M ± m). By knowing the number of injuries and the number of fire service officers at risk, we calculated the risks of injury for specific occupational scenarios.Results and discussion. The FFS officers of the EMERCOM of Russia are subject to the average annual risk of injury due to victims’ own negligence of (4.49 ± 0.62) ∙ 10–4 injuries / (person ∙ year). The risk of injuries commissioned officers (5.54 ± 0.87) ∙ 10–4 injuries/(person ∙ year) exceeds that among non-commissioned workers (3,14 ± 0,29) ∙ 10–4 (injuries/person ∙ year). Over 12 years, the incidence of injuries saw a 2.7-fold decrease among commissioned officers and a 1.4-fold decrease among non-commissioned workers. The share of injuries due to ‘victims’ own negligence’ stood at 36 % of the total number of occupational injuries among fire service officers.Conclusion. The analysis of injury scenarios due to ‘victims’ own negligence’ among the FFS officers of the EMERCOM of Russia is a contribution to enhance prevention of occupational injuries among firefighters and reduce the death rate in occupational settings.
Introduction. In 2021, the largest proportion of workers in the Russian Federation with class 3.1 and higher1 was at coal mining enterprises (79.1%), in coal mines this figure reached 90.4%, which determines the high level of occupational morbidity of miners — more than 150–200 times higher than the average in Russia2. The study aims to conduct a comprehensive analysis of the working conditions of employees of operating coal mines in Russia according to the data of the Federal State Statistics Service in comparison with the indicators of occupational morbidity (on the example of the Rostov region). Materials and methods. The authors have carried out the analysis of the data of the FSIS SAWC from 2018 to 2022 for all 57 coal mines operating in Russia during this period in four federal districts (FD) with a total number of jobs (RM) — 17,158, employing 60,699 people. The objects of the study were employees of 12 professions. For an integral assessment of the degree of harmfulness of working conditions of miners, we have calculated the total score of the degree of harmfulness of working conditions. Scientists investigated the occupational morbidity of miners. The experts also compared the established indicators with the data on the FSIS SAWC on the example of enterprises of the Rostov region (with the calculation of Spearman correlation coefficients). Results. Working conditions of 13% of miners belong to Class 3.1, 42% — to class 3.2, 35% — to class 3.3 and about 2% — to class 3.4. We have identified the most unfavorable conditions in the professions of tunnellers and longwall miner (721.9 and 717.1 points) — class 3.3–3.4; drivers of electric locomotives, drivers of hoisting installations, electricians, miners (hydraulic fracturing), explosives (500.3, 495.6, 444.3, 436.4 and 407.4 points) — class 3.2–3.3; among mining foremen, fasteners, stemmers, mechanics and lifting drivers (392.9, 333.3, 261.0, 256.8, 157.1 points), class — 3.2–3.1. The leading production factors are: the severity of labor (85.1%), noise (83.3%), aerosols of predominantly fibrogenic action (79.4%). Increased levels of local vibration, unfavorable microclimate and insufficient illumination are recorded at 30–40% of the RM. The authors found that only 2.4% of workplaces exceeded the maximum permissible level (MPL) for general vibration, and 0.3% — in terms of labor intensity. There is no data on infrasound, non-ionizing and ionizing radiation. Limitations. The study is limited to data on working conditions and occupational morbidity of coal miners for the period 2018–2022. These limitations allow us to plan further research and expand our understanding of this problem. Conclusion. The most unfavorable working conditions we have registered in the Southern Federal District, followed by the Siberian Federal District, Northwestern Federal District, Far Eastern Federal District, which is primarily due to the technologies used and production conditions. Also, scientists have identified underestimation of the degree of harmfulness of working conditions by factors (severity and intensity of work, local vibration, light environment, microclimate), non-accounting of ionizing radiation. The structure of the leading production factors determines the modern structure of occupational morbidity of miners: radiculopathy (39.2%), respiratory diseases (36.7%), diseases from exposure to noise and local vibration (18.2%). Ethics. The study did not require the conclusion of the Ethics Committee.
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