1922
DOI: 10.1039/ct9222100870
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XCIX.—Reactions of thiosemicarbazones. Part I. Action of halogen compounds

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Cited by 20 publications
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“…On the other hand lnost tscs dissolve in alkali (13,14) and form metallic complexes in alkaline solution ( 5 , 8,11) thus suggesting the important role of one of the anions (V) in solution. The observation that N2-methyl tscs (I, R3 = Me) do not dissolve in alkali (13) and that h3-clrazides of type (R-CO-NH-NRR)…”
mentioning
confidence: 99%
“…On the other hand lnost tscs dissolve in alkali (13,14) and form metallic complexes in alkaline solution ( 5 , 8,11) thus suggesting the important role of one of the anions (V) in solution. The observation that N2-methyl tscs (I, R3 = Me) do not dissolve in alkali (13) and that h3-clrazides of type (R-CO-NH-NRR)…”
mentioning
confidence: 99%
“…This is in agreement with siluilar findings that open-chain tscs exist only in the thiono form in the solid state (Is), and 3-mercapto-5-oxo-1,2,4-triazines were recently shown to exist in the lceto and thiono forms in neutral solution (16). I-Iowever, there is little doubt that in the presence of a base, the thione thiol tautoillerisnl takes place since both tscs and thiotriazine dissolve in alliali, and the S-Kc's salt of acetone tsc has already been described (17). As a comparison, the analogous 3-oxy-1,2,4-triazine (VIII) was prepared and its infrared For personal use only.…”
mentioning
confidence: 99%
“…Benzophenone thiosemicarbazone (I) was prepared by the known procedure (13) and its S-benzyl derivative (II) was obtained by benzylation with benzyl chloride in the presence of sodium ethoxide (14).…”
Section: Methodsmentioning
confidence: 99%