2011
DOI: 10.1016/s1005-0302(11)60070-4
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Yttria Tetragonal Zirconia Biomaterials: Kinetic Investigation

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Cited by 33 publications
(11 citation statements)
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“…In the presence of water from the wet veneering porcelain and high temperature during firing cycles (around 800 C); these microcracks act as stress concentration sites which grow further by migration of water into zirconia lattice starting the tetragonal-tomonoclinic phase transformation which is responsible for 3e5% volume increase [31] and thus, creating compressive stresses within the frameworks. These stresses, together with those caused by (core-veneer) CTEs mismatch, are thought to contribute to the marginal distortion developed during veneering of CAD/ CAM frameworks [33,41]. In the present study, attributing the marginal distortion during veneering of CAD/CAM zirconia frameworks to the [low temperature aging phenomenon together with the mismatch between core and veneer coefficients of thermal expansion] seems to be more reasonable rather than to the contraction forces developed from firing shrinkage of veneering porcelain because the high flexural strength and fracture toughness of zirconia [3] can resist its deformation under contraction forces.…”
Section: Discussionmentioning
confidence: 99%
“…In the presence of water from the wet veneering porcelain and high temperature during firing cycles (around 800 C); these microcracks act as stress concentration sites which grow further by migration of water into zirconia lattice starting the tetragonal-tomonoclinic phase transformation which is responsible for 3e5% volume increase [31] and thus, creating compressive stresses within the frameworks. These stresses, together with those caused by (core-veneer) CTEs mismatch, are thought to contribute to the marginal distortion developed during veneering of CAD/ CAM frameworks [33,41]. In the present study, attributing the marginal distortion during veneering of CAD/CAM zirconia frameworks to the [low temperature aging phenomenon together with the mismatch between core and veneer coefficients of thermal expansion] seems to be more reasonable rather than to the contraction forces developed from firing shrinkage of veneering porcelain because the high flexural strength and fracture toughness of zirconia [3] can resist its deformation under contraction forces.…”
Section: Discussionmentioning
confidence: 99%
“…The ability to preserve the tetragonal phase in PSZ at room temperature leads to favorable mechanical properties, especially a high K I C value. 1…”
mentioning
confidence: 99%
“…Têm geralmente temperaturas de fusão bastante elevadas e grande estabilidade química, o que lhes confere uma boa resistência à corrosão. (Elshazly, El-Hout, & Ali, 2011).…”
Section: Lista De Figurasunclassified
“…As medidas da cinética da degradação induzida pela umidade de cerâmicas sinterizadas, obtidas por difração de raios X ou espectroscopia Raman, indicam que no processo de transformação de fase isotérmica, a fração de volume transformada com o tempo pode ser expressa em termos da equação V de Mehl-Avrami-Johnson. (Chevalier et al, 2009), (Elshazly et al, 2011). Compilando dados de diferentes temperaturas, a curva da cinética das transformações tem a forma de "C" em um gráfico tempo-temperatura.…”
Section: Degradação a Baixa Temperatura (Ltd)unclassified
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