2003
DOI: 10.1023/a:1023310006090
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“…Molten alkali metal chlorides (MCl) are almost entirely ionic liquids. However, they also contain short-lived (with a lifetime of ∼10 –12 s) autocomplex anions of MCl n ( n – 1) (where n ≈ 4) type together with the M + elementary cations in the second coordination sphere. ,, In molten LiCl–KCl mixtures, the LiCl 4 3– complex ions are predominantly formed, and K + ions are in the second coordination sphere since the ionic potential of the Li + cation is much higher than the ionic potential of K + . The coordination number of Li + ≈ 4 in the LiCl–KCl eutectic was confirmed in ref by X-ray diffraction and molecular dynamics simulation.…”
Section: Discussionmentioning
confidence: 99%
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“…Molten alkali metal chlorides (MCl) are almost entirely ionic liquids. However, they also contain short-lived (with a lifetime of ∼10 –12 s) autocomplex anions of MCl n ( n – 1) (where n ≈ 4) type together with the M + elementary cations in the second coordination sphere. ,, In molten LiCl–KCl mixtures, the LiCl 4 3– complex ions are predominantly formed, and K + ions are in the second coordination sphere since the ionic potential of the Li + cation is much higher than the ionic potential of K + . The coordination number of Li + ≈ 4 in the LiCl–KCl eutectic was confirmed in ref by X-ray diffraction and molecular dynamics simulation.…”
Section: Discussionmentioning
confidence: 99%
“…The coordination number of Li + ≈ 4 in the LiCl–KCl eutectic was confirmed in ref by X-ray diffraction and molecular dynamics simulation. Relatively free K + cations in the second coordination sphere are the most mobile and their contribution to the melt electroconductivity is maximum. , …”
Section: Discussionmentioning
confidence: 99%
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