Hexagonal nanodisks of ZnO were fabricated by a solution process using ZnO nanoparticles and their cathodoluminescence characteristics were investigated. Monochromatic cathodoluminescence images showed that luminescence was spatially localized near the boundary of the nanodisk and spectral analysis in conjunction with the intensity profile consistently ascribed the spatial localization of luminescence to whispering-gallery-modelike-enhanced emission. © 2006 American Institute of Physics. ͓DOI: 10.1063/1.2174122͔With the successful demonstration of various nanostructures and increasing demand for integrable optoelectronic components with existing silicon technology, small-scale dielectric resonators applicable to photonic nanodevices with low-thresholds have gained importance because they can be used as low-power-consumption light sources in integrated circuits. Reducing the size of photonic devices, however, results in decrease of luminescence intensity in such a way that careful design of intensity enhancement mechanism should be introduced. For this reason, the whispering-gallery mode, which has been particularly utilized in applications to optical communication, has attracted much attention because it is a very efficient mechanism of luminescence enhancement even in small-scale resonators. 1-4 Since a top-down approach, such as lithography, has been among the best technological methods to fabricate tailored nanostructures appropriatue for specific research or application purposes, much effort has been made in order to fabricate nanoresonators via lithography to achieve low-threshold photonic nanodevices. There are, however, a few important generic problems in top-down fabrication of nanoresonators. There is unavoidable damage to films associated with lithographic etching process. An unwanted strain effect is also involved due to the limited choice of substrates to accommodate lattice misfit. In contrast, photonic nanodevices with bottom-up-based nanoscale resonant cavity employing whispering-gallery modes ͑WGMs͒ are very promising integrable components with high luminescence efficiency. More than that, a bottom-up approach typically does not depend on the choice of substrates, which is a major advantage in integration with current silicon technology.Due to direct and wide-band-gap characteristics with a large binding exciton energy, ZnO has drawn much attention for potential application to short-wavelength optoelectronic devices. In addition to single-crystalline ZnO thin films, ZnO nanowires and nanorods with perfect crystallinity were recently fabricated, and newly developed ZnO-based nanostructures demonstrated the possibility for nanoscale optoelectronic devices. [5][6][7] In contrast with one-dimensional nanostructures, such as nanorods, hexagonal nanodisk resonators employing WGMs have a smaller effective volume of gain medium, so that it is easier to fabricate compact photonic nanodevices. In addition, nanodisks are more confined to the surface of substrate and mechanical stability of nanodisks for pos...