“…In case of actively corroding metals such as iron/mild steel, loosely bound and non-protective oxide is formed at the metal/coating interface during sol-gel coating and subsequent heat treatment at higher temperatures results into poor coating properties [13]. Efforts have been made to overcome such problem by introducing iron/zinc phosphate interlayer prior to sol-gel deposition [14][15][16][17]. The phosphate interlayer has been shown to provide better adherence to sol-gel coating through mechanical interlocking.…”
“…In case of actively corroding metals such as iron/mild steel, loosely bound and non-protective oxide is formed at the metal/coating interface during sol-gel coating and subsequent heat treatment at higher temperatures results into poor coating properties [13]. Efforts have been made to overcome such problem by introducing iron/zinc phosphate interlayer prior to sol-gel deposition [14][15][16][17]. The phosphate interlayer has been shown to provide better adherence to sol-gel coating through mechanical interlocking.…”
“…An interesting and relatively recent possibility is the realization of protective films on metals and, particularly, the fabrication of coating films starting from metal alkoxides. Several coatings produced by sol-gel processing have been studied extensively for corrosion prevention in stainless steel and other metals that naturally form a passive layer on their surface [8][9][10], although sol-gel deposition on active corroding materials, such as iron, with a wide variety of coatings remains unexplored [11][12][13].…”
“…, 2001bVoevodin. , 2001c and, to a lesser extent, studies on carbon steels (Giampaolo 1997;Fallet 2001) , copper Boysen 1999), nickel, etc. Considering the nature of the coatings, they can be divided into two large groups: …”
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