The
impact of photoanode preparation on the photovoltaic performance
of dye-sensitized solar cells was investigated. The effects of titanium
dioxide layer thickness, type of solvent and immersion time used for
photoanode fabrication, and addition of coadsorbents and a cosensitizer
on photon-to-current conversion efficiency and photovoltaic parameters
were studied. Commercially available N719 and dyes prepared in our
research group, 5,5′-bis(2-cyano-1-acrylic acid)-2,2′-bithiophene
and 2-cyano-3-(2,2′:5′,2″-terthiophen-5-yl)acrylic
acid, were applied as sensitizers. The effect of studied factors on
UV–vis properties and morphology, that is, the root-mean-square
roughness of the photoanode, was examined and correlated with the
photovoltaic response of the constructed devices. Additionally, the
amount of dye molecules adsorbed to the TiO2 was investigated.
It was found that all considered factors significantly impacted photovoltaic
parameters. Also, the photoanode stability was tested by measuring
photovoltaic parameters after 14 months.