Zur Frage der Entstehung von Nitrosaminen bei der Reaktion von Monosacchariden mit Aminos�uren (Maillard-Reaktion) in Gegenwart von Natriumnitrit 2. Mitteilung

Heyns, Kurt; Röper, Harald; Koch, H.

doi:10.1007/bf01154871

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1977

1988

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Cited by 9 publications

(1 citation statement)

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“…Hodge (1953,1967) had reviewed the chemistry of browning reactions and pointed out that simple model reaction systems could be used to learn about the more complex food systems. Since then the formation of browning products has been investigated intensively by using model systems of a sugar and an amine (Heyns et al, 1974;Hodge et al, 1972; Koehler et al, 1969). Most of the studies have been concerned with the flavor chemistry of the browning reaction (Rizzi, 1972;Shibamoto and Bernhard, 1978; Sakaguchi and Shibamoto, 1978).…”

mentioning

confidence: 99%

Mutagenicity of the L-rhamnose-ammonia-hydrogen sulfide browning reaction mixture

Toda¹,

Sekizawa²,

Shibamoto³

1981

J. Agric. Food Chem.

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mentioning

confidence: 99%

Mutagenicity of the L-rhamnose-ammonia-hydrogen sulfide browning reaction mixture

Toda¹,

Sekizawa²,

Shibamoto³

1981

J. Agric. Food Chem.

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Untersuchungen zur MAILLARD‐Reaktion 2. Mitt. Zur Reaktion von Glucose mit Phenylalanin in Wasser

Westphal

Cieśłik

1981

Nahrung

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Mutagen formation in browning model systems

Shibamoto

1984

J of Applied Toxicology

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A browning model system, consisting of diacetyl and ammonia, produced frameshift and base-pair substitution mutagens when the system was heated over 20 min and 120 min, respectively. The major product was 2,4,5- trimethylimidazole , which showed no mutagenicity toward Salmonella typhimurium strains TA98 and TA100 with or without metabolic activation. When furfural was reacted with nitrate under mild conditions (for 30 min to 3 h at 0-25 degrees C and pH 2-7), it did not produce mutagenic nitrofuran derivatives. However, the ethyl ether extract obtained from the reaction mixture of furfural and nitrate with hydrochloric acid exhibited strong mutagenic activities toward S. typhimurium strains TA98 and TA100 in the presence of metabolic activation. The major product of this reaction mixture, 4- nitrofurfural , exhibited no mutagenicity toward tester strains TA98 and TA100 with or without metabolic activation. Pure active mutagen(s) was (were) not, however, identified in either system.

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Zur Frage der Entstehung von Nitrosaminen bei der Reaktion von Monosacchariden mit Aminos�uren (Maillard-Reaktion) in Gegenwart von Natriumnitrit 2. Mitteilung

Cited by 9 publications

References 14 publications

Mutagenicity of the L-rhamnose-ammonia-hydrogen sulfide browning reaction mixture

Mutagenicity of the L-rhamnose-ammonia-hydrogen sulfide browning reaction mixture

Untersuchungen zur MAILLARD‐Reaktion 2. Mitt. Zur Reaktion von Glucose mit Phenylalanin in Wasser

Mutagen formation in browning model systems

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