“…Among the carbonates, the aragonite-type structure is adopted by compounds with M II = Ca, Sr, Ba, Ra, Pb, or Eu (as well as Sm or Yb) [22][23][24]. Note that CaCO 3 is found with calcite structure at atmospheric pressure while the aragonite type is stable at elevated pressure, but also Crystal Space group Nonlinearity Room-temperature Manifestation of Span of Stokes SRS-promoting nonlinear-laser and anti-Stokes mode, cm −1 interaction comb, cm −1 a) SiO2 D 4 3 − P 3121 b) χ (2) + χ (3) 465.5 [11] SRS, SHG, THG c) , ≈ 20482(45) (α-quartz) (No. 152) self-SFG(SRS) d) [9,11] ≈ 8383 (19) [11] CaCO3 D 6 3d − R3c χ (3) 1086.5 [8,10] SRS, SHG e) , THG, FiHG f ) , ≈ 20643(20) (calcite) (No.…”