α-Hydroxyimine palladium complexes: Synthesis, molecular structure, and their activities towards the Suzuki–Miyaura cross-coupling reaction

Pd nanoparticles immobilized on magnetic chitosan as a novel reusable catalyst for green Heck and Suzuki cross‐coupling reaction: In water at room temperature

“…In recent years, extensive studies have been done to designing new catalytic system with the unique ability to provide excellent catalytic generality and activity . In this regard, palladium catalysts employed electron rich phosphine ligands, nitrogen containing ligands, heterocyclic carbenes, oximes, and imines has been reported, these catalysts suffer from air and moisture sensitivity. However, recent efforts have been devoted toward of development in reduction of chemical waste, safer and more efficient reaction conditions.…”

Aerobic and Efficient Direct Arylation of Five-Membered Heteroarenes and Their Benzocondensed Derivatives with Aryl Bromides by Bulky α-Hydroxyimine Palladium Complexes

“…Recently, we have developed types of nitrogen-based α-hydroxyimine palladium complexes which were highly efficient for Suzuki–Miyaura cross-couplings under aerobic conditions at a temperature of 60 °C . Because a higher reaction temperature is employed in C–H activation, we envisioned that strong binding of the electron-rich and bulky N,O-based ligands will help the palladium retain its ligand and retard the decomposition of the catalyst.…”

Recent Developments in the Suzuki-Miyaura Reaction: 2010–2014

“…The same year, Ramesh reported the synthesis of complex 34 for the coupling of deactivated aryl bromides and bromopyridines [62]. More recently, Shin and Liu used complex 35 as catalyst for the coupling of a variety of bromides at mild temperatures (rt—60 °C) [63].…”