(β-Diketiminato)aluminum hydroxides and the chalcogenide derivatives: Precursors for homo- and heterometallic complexes with Al-E-M (E = chalcogen, M = metal) frameworks

A Mesoionic Diselenolene Anion and the Corresponding Radical Dianion

“…2.50 Å) are within the range reported for other Al(III) selenato complexes. [16] The SeÀ Al bonds (av. 2.55 Å) in 5 are slightly longer than those of 4.…”

Diversity of transformation of heteroallenes on acenaphthene-1,2-diimine aluminum oxide

“…[24][25][26] β-Diketiminatoaluminum oxides, in turn, undergo controlled hydrolysis to afford organometallic complexes with terminal Al-OH moiety, which attract an attention as potential building blocks for heterobimetallic complexes. 27 The resulting gallium hydride catalyzes addition of PhSiH 3 to Ph(H)CvO. 29 Whereas in hydroboration reactions of the aluminum diolate complex [{(dpp-bian)Al(μ-O 2 CH 2 )} 2 ], obtained by capture of CO 2 with acenaphthene-1,2-diimine aluminum hydride, the Al-O/B-H metathesis is not observed.…”

(Bipyridine bisphenolate)-aluminum/onium salt pair: a highly active binary catalyst for ring-opening polymerization of lactide with improved thermostability and protic tolerance

“…Organometallics are one class of versatile catalytic systems for ROP, because their catalytic performance can be easily modulated by tuning the Lewis acidity of the metal centre and modifying the electronic or steric effects of the ligand backbone. 34–36 Besides, organometallics can achieve a high degree of control over the stereoregularity of the polymer chain, compared with organocatalysts and Lewis pairs. 9,37–45…”

“…Organometallics are one class of versatile catalytic systems for ROP, because their catalytic performance can be easily modulated by tuning the Lewis acidity of the metal centre and modifying the electronic or steric effects of the ligand backbone. [34][35][36] Besides, organometallics can achieve a high degree of control over the stereoregularity of the polymer chain, compared with organocatalysts and Lewis pairs. 9, [37][38][39][40][41][42][43][44][45] Salen-metal complexes have prevailed in the ROP of lactone, because the steric and electronic effects of the ligand can be easily modulated by chemical modification.…”