μ‐Nitrido‐Bis(Triphenylphosphorus)(1+) Undecacarbonylhydridotriferrate(1‐), [(Ph
 3
 P)
 2
 N][Fe
 3
 H(Co)
 11
 ]

The interest in transition metal cluster catalysis has developed tremendously over the past decade because of the potential benefits metal cluster compounds may provide over traditional catalysts. Although these expectations have not been met yet transition metol cluster catalysis has offered many insights into the phenomenon of catalgsis and still remains the most important driving ,force of the metal cluster chemistry. This part of the review on transition metal cluster compounds deals with the homogeneous and heterogeneous catalysis by such compounds. Hydrido-alkenyl-Cluster abreagieren kann. OEt I , H 2 J E t OOC -CH2-C H 2 -COOEt / \ 0 s -\ /"' TI : 0 s O&-Os / \ ' H ' Z . Cliein. 29. .lg. (1989) lIe/t 4 Erhalt des Ru,-Clustergeriistes vor, Zyklus (7) (Schema 2).

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Interaction of carbonylferrate- and hydridocarbonylferrate anions with Brønstad and Lewis acids

Belousov

1997

Russ Chem Bull

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Interaction of carbonyiferrate anions Fen(CO)I~,T_4 and hydridocarbonylferrate anions HFen(CO)~. q (where n = I--4; m = 5, 9, 12, 14, respectively) with Bronstad and Lewis acids HX (X = AcO, CF3CO 2, HSO4) and RX(R = Alk, Ac, Bn, Bz; X = CI, Br) isa radical-chain process, oecuring via a one-electron redox-initiation stage, including preliminary activating complex formation. A common approach to the description of the processes of reduction and carbonylation of different organic compounds was suggested. It is based upon the exchange reactions and the interconversions within the coordination spheres of 17-electron coordinatively unsaturated iron earbonyl radical anions. Fe,(CO)",~T--I-

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μ‐Nitrido‐Bis(Triphenylphosphorus)(1+) Undecacarbonylhydridotriferrate(1‐), [(Ph ₃ P) ₂ N][Fe ₃ H(Co) ₁₁ ]

Cited by 14 publications

References 10 publications

In Bi‐ and Polynuclear Metal Carbonyl Anions and Carbonyl Hydrides

In Bi‐ and Polynuclear Metal Carbonyl Anions and Carbonyl Hydrides

Metallclusterverbindungen  Chemie und Bedeutung; Homogene und heterogene Katalyse

Interaction of carbonylferrate- and hydridocarbonylferrate anions with Brønstad and Lewis acids

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μ‐Nitrido‐Bis(Triphenylphosphorus)(1+) Undecacarbonylhydridotriferrate(1‐), [(Ph 3 P) 2 N][Fe 3 H(Co) 11 ]

Cited by 14 publications

References 10 publications

In Bi‐ and Polynuclear Metal Carbonyl Anions and Carbonyl Hydrides

In Bi‐ and Polynuclear Metal Carbonyl Anions and Carbonyl Hydrides

Metallclusterverbindungen  Chemie und Bedeutung; Homogene und heterogene Katalyse

Interaction of carbonylferrate- and hydridocarbonylferrate anions with Brønstad and Lewis acids

Contact Info

Product

Resources

About

μ‐Nitrido‐Bis(Triphenylphosphorus)(1+) Undecacarbonylhydridotriferrate(1‐), [(Ph ₃ P) ₂ N][Fe ₃ H(Co) ₁₁ ]