μ-Oxo-bis[<i>N</i>,<i>N</i>'-ethylenebis(2-thioacetophenonidenimine)iron(III)]

Karsten, P.; Strähle, Joachim

doi:10.1107/s0108270198014826

Cited by 4 publications

(3 citation statements)

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“…The most obvious derivatization is replacement of the aldimine hydrogen with a methyl group, affording the simplest ketimine (Scheme ). To our knowledge only a few previous examples of this ligand class exist, all being of the tetradentate type prepared by templated routes discussed previously . We found that the ketimines derived from sterically unhindered anilines can be prepared directly and in good yield if the reaction mixtures are kept at ambient temperature.…”

Section: Resultsmentioning

confidence: 99%

Platinum Group Thiophenoxyimine Complexes: Syntheses and Crystallographic/Computational Studies

2007

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Monomeric thiosalicylaldiminate complexes of rhodium(I) and iridium(I) were prepared by ligand transfer from the homoleptic zinc(II) species. In the presence of strongly donating ligands, the iridium complexes undergo insertion of the metal into the imine carbon−hydrogen bond. Thiophenoxyketimines were prepared by nontemplated reaction of o-mercaptoacetophenone with anilines and were complexed with rhodium(I), iridium(I), nickel(II), and platinum(II). X-ray crystallographic studies showed that while the thiosalicylaldiminate complexes display planar ligand conformations, those of the thiophenoxyketiminates are strongly distorted. Results of a computational study predicted that all synthetically accessible thiophenoxyketiminates will display distorted geometries.

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Section: Resultsmentioning

confidence: 99%

Platinum Group Thiophenoxyimine Complexes: Syntheses and Crystallographic/Computational Studies

2007

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“…The Co 2+ complex 116 is dimeric with a Co 2 S 2 diamond core . A chloride completes the pentacoordination environment about Fe 3+ in 117 , while a μ-O bridges two Fe III N 2 S 2 units of 118 . The hexacoordinate, octahedral complex 119 features the thiosalen ligand with a CO and pyridine ligand in the axial positions .…”

Section: Monometallic Systems or The Metalloligandsmentioning

confidence: 99%

“…113 A chloride completes the pentacoordination environment about Fe 3+ in 117, 114 while a μ-O bridges two Fe III N 2 S 2 units of 118. 115 The hexacoordinate, octahedral complex 119 features the thiosalen ligand with a CO and pyridine ligand in the axial positions. 116 Complex 120 is a dimeric ZnN 2 S 2 with the familiar Zn 2 S 2 core lending pentacoordination to Zn.…”

Section: Chemical Reviewsmentioning

confidence: 99%