(π‐Allyl)Pd Complexes Containing N‐Heterocyclic Carbene and Pseudohalogen Ligands – Synthesis, Reactivity toward Organic Isothiocyanates and Isocyanides, and Their Catalytic Activity in Suzuki–Miyaura Cross‐Couplings

Abstract

Große Einkristalle des chiralen Ferrimagneten [{Cr(CN)6}{Mn(S)‐pnH(H2O)}](H2O) entstehen bei der Reaktion von K3[Cr(CN)6], Mn(ClO4)2 und (S)‐1,2‐Diaminopropan‐Dihydrochlorid (siehe Bild; (S)‐pn=(S)‐1,2‐Diaminopropan). Die MnII‐ und CrIII‐Zentren der Verbindung wechselwirken ferrimagnetisch; die Übergangstemperatur beträgt 38 K.

Synthesis and Structure of Multinuclear Pd(II) Complexes Bridged by Phosphide or Azide Ligands

“…We had reported that Pd­(II)–chloride complexes could undergo facile conversion to the corresponding Pd­(II)–azide complexes by reaction with NaN 3 in an H 2 O/CH 2 Cl 2 two-phase system. , When this method was applied to the chloride-bridged Pd­(II) dinuclear complex [PdCl­(μ-Cl)­(PEt 3 )] 2 ( 3a ), the corresponding azide-bridged Pd­(II) dinuclear complex [Pd­(N 3 )­(μ-N 3 )­(PEt 3 )] 2 ( 4 ) was formed in 47% isolated yield. On the other hand, the reaction of the chloride-bridged Pd­(II) dinuclear complex [PdCl­(μ-Cl)­(PPhMe 2 )] 2 ( 3b ) with NaN 3 in H 2 O/CH 2 Cl 2 did not afford the analogue of 4 but afforded an azide-bridged Pd­(II) tetranuclear complex [Pd­(N 3 )­(μ-N 3 )­(PPhMe 2 )] 4 ( 5 ) in 50% yield.…”

Role of the auxiliary ligand in determining the genotoxicity and mode of cell death of thiosemicarbazone Pd(ii) complexes

“…1). [43][44][45] Tetrazolate complex 8, was characterized by a variety of spectroscopic and analytical tools. Unfortunately, despite numerous tries, no crystal suitable for X-ray crystallographic analysis could be isolated.…”

Reactivity of azido terpyridine Pd(ii) and Pt(ii) complexes towards 4,4,4-trifluoro-2-butynoic acid: structural insight into the triazolato coordination mode

“…1 Kim and coworkers discovered that the click reactions of azido square-planar complexes with isothiocyanates proceeded site-specically yielding tetrazole-thiolato bound complexes. 17,18 Pd(II) thiolato-tetrazolate complexes, with N,N,N-tridentate ligands, have recently shown higher antifungal activity (MIC = 0.31 mM) against Cryptococcus neoformans and Candida albicans than their comparable chlorido complexes (MIC = 0.95-1.90 mM) and the reference medication Fluconazole (MIC = 0.41-26.1 mM). 10 Recently, it was examined how four different alkynes reacted to two square-planar Pd(II) and Pt(II) complexes functionalized with the N,N,S-tridentate ligand.…”