The article considers the results of studies of the emission spectra of Kr, Xe upon excitation by pulsed laser radiation. We used Nd: YAG laser, λ = 1064 nm, τ = 5 ns, and Epulse = 0.8 J. The spectral range of 30-200A was studied. We used capillary with d = 500 μm and supersonic conical nozzles with dcr = 145 μm, 2α = 12o, L = 5 mm, and dcrit = 450 μm, 2α = 11o, L = 5 mm to form a gas jet. The emission spectra for various gas targets were obtained, the obtained spectra were deciphered, and the ions emitting in this spectral range were determined. We observed that with increasing particle concentration in the zone of laser spark, the radiation intensity increases. In this case, the intensity of ion lines with high degrees of ionization increases faster.