Considerable progress has been made over the last decades in thermal spray technologies, practices and applications. However, like other technologies, they have to continuously evolve to meet new problems and market requirements. This article aims to identify the current challenges limiting the evolution of these technologies and to propose research directions and priorities to meet these challenges. It was prepared on the basis of a collection of short articles written by experts in thermal spray who were asked to present a snapshot of the current state of their specific field, give their views on current challenges faced by the field and provide some guidance as to the R&D required to meet these challenges. The article is divided in three sections that deal with the emerging thermal spray processes, coating properties and function, and biomedical, electronic, aerospace and energy generation applications.
Polymer-derived ceramics (PDCs) such as silicon oxycarbide (SiOC) have shown promise as electrode materials for rechargeable Li-ion batteries (LIBs) owing to the synergy between their disordered carbon phase and hybrid bonds of silicon with oxygen and carbon. This study describes the synthesis and characterization of a new type of PDC composite comprising SiOC embedded with varying wt% of boron nitride nanotubes (BNNTs) and supported on reduced graphene oxide. Electron microscopy and a range of spectroscopic characterization techniques were employed to confirm the polymer-to-ceramic transformation and presence of a disordered carbon phase. The composites were tested as electrode materials for LIB and symmetric supercapacitor applications. As an electrode material for LIB, SiOC-BNNT paper composite containing 0.25 wt% BNNT demonstrated the highest charge capacity of 410 mA h g À1 (at 100 mA g À1 ) which stabilized at 238 mA h g À1 . On the contrary, composite electrode with 0.5 wt% BNNT demonstrated the highest specific capacitance corresponding to 78.93 F g À1 at 1 A g À1 with a cyclic retention of 86% after 185 cycles. This study shows that presence of BNNTs in the composite influenced the free carbon phase in SiOC and its electrochemical performance. As such, the composite may be used as a flexible electrode material for electrochemical energy storage devices.
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