The exciton binding energies are measured in GaN grown on A-plane sapphire. A value of 25Ϯ1 meV is found to be consistent with reflectance and photoreflectance experiments. This 25 meV value matches very well the results obtained on GaN epilayers grown on C-plane sapphire with strong biaxial compression, and seems to indicate that exciton energies in GaN epilayers are predominantly influenced by strain fields. From the in-plane anisotropy of optical response, we deduce a value of Ϫ2.4 eV for the C 5 deformation potential in GaN. ͓S0163-1829͑98͒03508-5͔
This work is a study relating device performance and carrier escape sequence in a large set of InAsP∕InP p-i-n multi-quantum-well solar cells. The devices encompass nearly identical i-region thickness and built-in electric field and present similar absorption threshold energies. The escape sequence of the first confined electron-to-conduction band continuum and heavy/light holes-to-valence band continuum is extracted from the photoluminescence versus temperature analysis and by comparing the measured activation energies to calculated hole/electron well depths and thermionic escape times. Light holes, as expected for most III-V nanostructure systems, are found to be the fastest escaping carriers in all samples. The escape of electrons prior to heavy holes is shown to be a prerequisite to prevent severe open circuit voltage degradation. A possible explanation of the origin of this effect is offered. InP∕InAsP multi-quantum-well solar cells with high built-in electric field and fast electronic escape time display better open circuit voltage and performance.
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