When using gaseous fuels for the C.F.R. engine, the lubricating oil decomposed to finely divided carbon when the gas was hydrogen and optimum spark advance nearly zero. When town gas was used, optimum spark advance varied from 85 to 15 degrees of crank angle, according to mixture strength, and the lubricant yielded carbon of the hard adherent graphitic variety. When using an L head engine having a combustion chamber with a large surface-to-volume ratio and with the spark plug so placed that optimum spark advance for town gas was approximately half that required with the C.F.R. engine, no appreciable carbon deposit of any variety was obtained. Conditions were therefore such that knocking combustion observed on adding finely divided carbon to the gas–air mixture was not caused to any appreciable degree by carbon derived from the lubricant. It was then found on adding carbon, as graphite dust, at a measured rate to the entering mixture, that approximately 0.3 mgm. in the end gas caused a knock intensity of the degree required to reduce brake horsepower by from 10 to 14%.
Experimental results are given for trials of the C.F.R. engine at 900 r.p.m. and 12: 1 C.R. on Toronto town gas alone and with an addition of hydrogen sulphide. The sulphide led to such severe preignition that measurements of power were impossible except for very weak or very rich mixtures. The former included the 50% weak mixture for which thermal efficiency is a maximum. The sulphide was then of beneficial effect, a maximum value of 44% for indicated thermal efficiency being obtained as compared to a maximum of 42.5% without it. The experimental results are interpreted in the light of combustion tube experiments showing that hydrogen in mixtures with air is not ignited by red hot surfaces on which it is oxidized with sufficient rapidity to steam, but that ignition occurs at relatively low temperatures if the surface reaction is inhibited by hydrogen sulphide. The conclusion is that fuel gases containing hydrogen in large proportion can be used for full power engine operation at compression ratios even higher than 12: 1 if the oxidation of the hydrogen in part to steam, on the hot surfaces in the combustion chamber, is not inhibited by the poisoning effect of the hydrogen sulphide commonly present in the gases.
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