We report ferroelectric ordering in Ni substituted CaBaCo 4 O 7 . Magnetization showed ferrimagnetic transition at 60 K and an additional transition is found ~ 82 K, further, enhanced antiferromagnetic interactions and decrease in saturation magnetization are noticed with Ni substitution. The dielectric and pyroelectric measurements illustrate a strong coupling between spin and charge degrees of freedom; ferroelectric behavior is confirmed with enhanced ordering temperature (~82 K) and saturation polarization (250 μC/m 2 ). Neutron diffraction has revealed an increase in c-lattice parameter in Ni sample and all the Co/Ni moments are reoriented in a-direction; evidently a noncollinear ferrimagnetic to collinear ferrimagnetic spin order is observed. The coupling between the triangular and Kagome layers weakens and leads to ↑↑↓↓ AFM ordering in the Kagoma layer. This can be viewed as a 2D-collinear layer with unequal bond distances and most likely responsible for the switching of electric polarization.
Double perovskite type compounds of the formula BaA'LaTeO6 (A' = Na, K, Rb) were synthesized by solid state route and their crystal structures were determined by Rietveld analysis using powder X-ray diffraction and neutron diffraction data. Na compound crystallizes in the monoclinic system with P2₁/n space group whereas, K and Rb compounds crystallize in Fm3m space group. All the three compounds show rock salt type ordering at B site. Crystal structure analysis shows that La ion occupies A site in Na compound whereas, it occupies B site in K and Rb compounds according to the general formula of AA'BB'O6 for a double perovskite type compound. Effect of this crystallographic site swapping of the La ion was also observed in the photoluminescence study by doping Eu(3+) in La(3+) site. The large decrease in the intensity of the electric dipole ((5)D0-(7)F2) transition in the Rb compound compared to the Na compound indicates that Eu(3+) ion resides in the centrosymmetric octahedral environment in the Rb compound.
The role of doping Fe on the structural, magnetic, and dielectric properties of frustrated antiferromagnet YMn1−xFexO3 (x ≤ 0.5) has been investigated. The neutron diffraction analysis shows that the structure of these polycrystalline samples changes from hexagonal phase (space group P63cm) to orthorhombic phase (space group Pnma) for x > 0.2. The frustration parameter decreases with Fe substitution. All the compounds are antiferromagnetic, and the magnetic structure is described as a mixture of Γ3 and Γ4 irreducible representation (IR) in the hexagonal phase, and the ratio of these two IRs is found to vary with Fe doping (x ≤ 0.2). A continuous spin reorientation as a function of temperature is observed in these samples. The magnetic ground state in the orthorhombic phase of the higher doped samples (x ≥ 0.3) is explained by taking Γ1 (GxCyAz) representation of Pnma setting. In YMnO3 suppression of dielectric constant ε′ is observed below TN indicative of magnetoelectric coupling. This anomalous behavior reduces in Fe doped samples. The dielectric constant is found to be correlated with the magnetic moment (M) obtained from neutron diffraction experiments and follows a M2 behavior close to TN in agreement with Landau theory.
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