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-In this study, the fixed-bed adsorption of carbon dioxide and a carbon dioxide-nitrogen mixture on zeolite 13X was investigated. The adsorption equilibrium and breakthrough curves were determined at different temperatures -301-306 K, 323 K, 373 K and 423 K. A model based on the LDF approximation for the mass transfer, considering the energy and momentum balances, was used to describe the adsorption kinetics of carbon dioxide and a carbon dioxide-nitrogen mixture. The model acceptably reproduced all of the breakthrough curves and can be considered as adequate for designing a PSA cycle to separate carbon dioxidenitrogen mixtures.

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-Separation of CO 2 from CO 2 -CH 4 mixtures is an important issue in natural gas and biogas purification. The design of such separation processes depends on the knowledge of the behavior of multicomponent adsorption, particularly that of CO 2 -CH 4 mixtures. In this study, we present a series of experimental binary equilibrium isotherms for CO 2 -CH 4 mixtures on an activated carbon at 293 K and compare them with predicted values using the Ideal Adsorption Solution Theory (IAST) and the Extended Langmuir (EL) model. Even at concentrations of ca. 20% for all binary isotherms, CO 2 already presents higher adsorbed amounts with respect to CH 4 . A maximum selectivity of around 8.7 was observed for a nearly equimolar mixture at 0.1 MPa. The IAST in conjunction with the Toth equation showed slightly better results than IAST using the Langmuir equation and both showed better results than the EL model.

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