This paper presents the manufacturing method of silver based composite materials containing 3 % vol. carbon forms (nanotubes and graphene). The most significant challenge was to obtain good dispersion of carbon in the metallic matrix. The applying of suitable dispersants allows to get uniform distribution of carbon reinforcement. Triton X-100 and ultrasonic support were used in the powder mixing process. Ag-nanotubes and Ag-graphene contact tips were made using Spark Plasma Sintering process (SPS). The results of research into both physical and electrical properties of these composites are presented. It has been demonstrated that the form of introduced carbon exerts influence on the electrical characteristics of contacts, and particularly on arc erosion. Performed electrical test indicated that Ag-nanotubes contacts showed higher resistance to arc erosion than Ag-graphene contacts. It can be explained by the better dispersion to individual carbon nanotubes their lower than for graphene edge defects density and due to this higher thermal and electrical conductivity.
The electrical properties and photoluminescence spectra ofLEC gallium arsenide crystals after neutron transmutation doping (NTD) have been investigated as function ofstarting material properties, irradiation dose and thermal to fast neutron fluence ratio.The residual carbon acceptors interact with radiation induced defects (RD) in neutron irradiated GaAs crystals and form nonradiative recombination centers, which are stable up to 700 °C.
The main current of publication is focused around the issues and problems associated with the formation of composite materials with Cu matrix and reinforcing phases in the various carbon nanoforms. The core of the research has been focused on thermal conductivity of these composites types. This parameter globally reflects the state of the structure, quality of raw materials and the technology used during the formation of composite materials. Vanishingly low affinity of copper for carbon, multilayered forms of graphene, the existence of critical values of graphene volume in the composite are not conducive to the classic procedures of composites designing. As a result, the expected, significant increase in thermal conductivity of composites is not greater than for pure copper matrix. Present paper especially includes: (i) data of obtaining procedure of copper/graphene mixtures, (ii) data of sintering process, (iii) the results of structure investigations and of thermal properties. Structural analysis revealed the homogenous distribution of graphene in copper matrix, the thermal analysis indicate the existence of carbon phase critical concentration, where improvement of thermal diffusivity to pure copper can occur.
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