Wildfires have a significant adverse impact on air quality in the United States (US). To understand the potential health impacts of wildfire smoke, many epidemiology studies rely on concentrations of fine particulate matter (PM) as a smoke tracer. However, there are many gas-phase hazardous air pollutants (HAPs) identified by the Environmental Protection Agency (EPA) that are also present in wildfire smoke plumes. Using observations from the Western Wildfire Experiment for Cloud Chemistry, Aerosol Absorption, and Nitrogen (WE-CAN), a 2018 aircraft-based field campaign that measured HAPs and PM in western US wildfire smoke plumes, we identify the relationships between HAPs and associated health risks, PM, and smoke age. We find the ratios between acute, chronic noncancer, and chronic cancer HAPs health risk and PM in smoke decrease as a function of smoke age by up to 72% from fresh (<1 day of aging) to old (>3 days of aging) smoke. We show that acrolein, formaldehyde, benzene, and hydrogen cyanide are the dominant contributors to gas-phase HAPs risk in smoke plumes. Finally, we use ratios of HAPs to PM along with annual average smoke-specific PM to estimate current and potential future smoke HAPs risks.

Wildland firefighters are exposed to smoke-containing particulate matter (PM) and volatile organic compounds (VOCs) while suppressing wildfires. From 2015 to 2017, the U.S. Forest Service conducted a field study collecting breathing zone measurements of PM 4 (particulate matter with aerodynamic diameter ≤4 μm) on wildland firefighters from different crew types and while performing various fire suppression tasks on wildfires. Emission ratios of VOC (parts per billion; ppb): PM 1 (particulate matter with aerodynamic diameter ≤1 μm; mg/m 3 ) were calculated using data from a separate field study conducted in summer 2018, the Western Wildfire Experiment for Cloud Chemistry, Aerosol Absorption, and Nitrogen (WE-CAN) Campaign. These emission ratios were used to estimate wildland firefighter exposure to acrolein, benzene, and formaldehyde. Results of this field sampling campaign reported that exposure to PM 4 and VOC varied across wildland firefighter crew type and job task. Type 1 crews had greater exposures to both PM 4 and VOCs than type 2 or type 2 initial attack crews, and wildland firefighters performing direct suppression had statistically higher exposures than those performing staging and other tasks (mean differences = 0.82 and 0.75 mg/m 3 ; 95% confidence intervals = 0.38−1.26 and 0.41−1.08 mg/m 3 , respectively). Of the 81 personal exposure samples collected, 19% of measured PM 4 exposures exceeded the recommended National Wildland Fire Coordinating Group occupational exposure limit (0.7 mg/m 3 ). Wildland fire management should continue to find strategies to reduce smoke exposures for wildland firefighters.

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COVID-19's impact on society and our daily habits has been unprecedented. With a decrease in vehicular traffic and industrial production, a decrease in local emissions was expected to occur. In order to capture any trends in ambient trace gas concentrations, approximately one thousand whole air samples were collected in intervals across the United States from April to July 2020 as part of the NASA Student Airborne Research Program (SARP). These samples were then analyzed by the UCI Rowland-Blake Lab using multi-column gas chromatography for over one hundred unique trace gases, including methane, non-methane hydrocarbons, and halocarbons, as described in Colman et al. (2001) and Barletta et al. (2002). Initial samples collected in April coincided with the peak of stay-at-home/social distancing orders in most states while samples collected later in the spring and early summer reflect the easing of these measures and initial state reopenings. Overall trends in emissions over time in select metropolitan areas will be discussed and compared to trends observed across the entire United States.