Abstract-Two dark lithic fragments and matrix of the Krymka LL3.1 chondrite were mineralogically and chemically studied in detail. These objects are characterised by the following chemical and mineralogical characteristics, which distinguish them from the host chondrite Krymka: (1) bulk chemical analyses revealed low totals (systematically lower than 94 wt%) due to high porosity; (2) enrichment in FeO and depletion in S, MgO and Si02 due to a high abundance of Fe-rich silicates and low sulfide abundance; (3) fine-grained, almost chondrule-free texture with predominance of a porous, cryptocrystalline groundmass and fine grains; (4) occurrence of a small amount of oncemolten material (microchondrules) enclosed in fine-grained materials; ( 5 ) occurrence of accretionary features, especially unique accretionary spherules; (6) high abundance of small calcium-aluminiumrich inclusions (CAIs) in one of the fine-grained fragments. It is suggested that the abundance of CAIs in this fragment is one of the highest ever found in an ordinary chondrite.Accretionary, fine-grained spherules within one of the fragments bear fundamental information about the initial stages of accretion as well as on the evolution of the clast, its incorporation, and history within the bulk rock of Krymka. The differences in porosity, bulk composition, and mineralogy of cores and rims of the fine-grained spherulitic objects allow us to speculate on the following processes: (1) Low velocity accretion of tiny silicate grains onto the surface of coarse metal or silicate grains in a dusty region of the nebula is the beginning of the formation of accretionary, porous (fluffy) silicate spherules. (2) Within a dusty environment with decreasing silicate/(metal + sulfide) ratio the porous spherules collected abundant metal and sulfide particles together with silicate dust, which formed an accretionary rim. Variations of the silicate/(sulfide + metal) ratio in the dusty nebular environment result in the formation of multi-layered rims on the surface of the silicate-rich spherules. (3) Soft accretion and lithification of rimmed, fluffy spherules, fine-grained, silicate-rich dust, metal-sulfide particles, CAIs, silicate-rich microchondrules, and coarse silicate grains and fragments followed. (4) After low-temperature processing of the primary, accretionary rock collisional fragmentation occurred, the fragments were subsequently coated by fine-grained material, which was highly oxidized and depleted in sulfides. ( 5 ) In a final stage this accretionary "dusty" rock was incorporated as a fragment within the Krymka host.
The Krymka chondrite contains an exotic graphite-beating fragment that appears to be of a new type of material added to unequilibrated LL-chondrite during agglomeration on the surface of the parent body. The fine-granular texture without chondrules, two morphological groups of graphite crystals which differ in size and occurence, high content of troilite (11.3 vol.%), the high Ni (55.5-66.6 wt.%) and Co (1.59-2.87 wt.%) contents of the taenite and absence of kamacite, the presence of F-apatite, which is rare for meteorites but common for lunar and terrestrial igneous rocks, are the main features of the fragment.The mineralogy and texture indicate: (1) the fragment probably formed by crystallization from a highly reduced silicate melt, which had been enriched in carbon; 2) the subsequent metal sulphidization lowered its abundance and resulted in the formation of troilite and the compositional features of the residual metal; (3) terrestrial weathering of an exotic fragment and the host part of the chondrite produced iron hydroxides, pentlandite and quite possibly magnetite.
Abstract-The Galkiv chondrite is a single 5 kg stone that fell in the Chernigov region of Ukraine on 1995 January 12. The composition of olivines in the meteorite indicate that Galkiv belongs to the H group of ordinary chondrites. Although the heterogeneity of olivine corresponds to a petrologic type 5 and the heterogeneity of low-Ca pyroxene suggests the chondrite is type 3, clearly defined chondrule boundaries, the presence of clinopyroxene, cryptocrystalline glass and rare grains of feldspatic plagioclase, structural evidences of shock metamorphism and very low level of terrestrial weathering allow us to classify the meteorite as an H4 chondrite of shock stage S3 and weathering grade WO.
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