ResumoO estudo de materiais de alto desempenho e multifuncionais, como os compósitos poliméricos cimentícios, tem sido o foco de inúmeras pesquisas na indústria da construção civil. Este trabalho investiga o efeito da combinação de uma fase polimérica termorrígida, uma resina epóxi, com cimento Portland branco estrutural, seguido da avaliação da resistência à compressão e módulo de elasticidade. Este compósito, quando comparado individualmente com as suas matérias-prima originais, promove um aumento da resistência mecânica à compressão, redução da massa específica e, também uma mudança significativa do comportamento mecânico. As mudanças nas propriedades mecânicas estão associadas à hidratação da fase cimentícia na presença da resina, fato comprovado através da análise espectroscópica na região do infravermelho. Palavras-chave: compósito cimentício polimérico, resina epóxi, cimento Portland branco, espectroscopia por infravermelho. AbstractThe study of multi-functional materials of high performance, as the polymeric-cementitious composites, has been the focus of several researches in the industry of the civil engineering. This work investigates the effect of the combination of a thermorigid epoxy phase and the white Portland cement, followed by the evaluation of its compressive strength and modulus of elasticity. This composite, when the phases are individually compared, provides an increase of the compressive strength, a reduction of the density, and a significant change of the mechanical behaviour. The changes in mechanical behaviour are associated with the hydration of cement in the presence of resin, which was evident after infrared spectroscopy analysis.
The intermetallic compound, RuAl with B2 CsCl type structure, has been shown to possess room-temperature toughness and plasticity. NiAl also forms a B2 compound and it is claimed that a pseudo-binary compound, (Ru,Ni)Al, may be formed because the difference in lattice parameter between the two binary phases is slight. In this work a study has been made of the mechanical properties of some polycrystalline compounds, across the RuAl-(Ru,Ni)Al pseudo-binary, prepared from high-purity elemental powders. Compressive yield stresses were measured between room-temperature and 900°C, and the mechanisms of plastic flow are discussed in relation to the dislocation structures observed by TEM. Hot-microhardness tests were made to provide an indication of the effect of solid-solution hardening.
RESUMOCom o objetivo de conhecer a influência das partículas AlB 2 e AlB 12 na capacidade de refino de grão de uma liga Al-4B sobre ligas de fundição à base de alumínio-silício, realizou-se testes de refino TP1 da Aluminum Association variando-se as concentrações de AlB 2 e AlB 12 . Para a caracterização química foram utilizadas as técnicas de espectrometria de emissão óptica e espectrometria de energia dispersiva (EDS). O método utilizado para medir os tamanhos de grão foi o do intercepto, através de uma lupa estereoscópica. Os resultados foram comparados com os do refinador convencional Al-5Ti-1B. A liga alumínio-silício utilizada foi a Al11Si-0,1Mg, comum na produção de rodas automotivas. A liga Al-4B com 100% de partículas AlB 2 apresentou a melhor capacidade de refino, proporcionando tamanhos médios de grãos de 0,26 mm na liga Al-11Si-0,1Mg, no tempo de amostragem de 5 minutos. A liga Al-4B com 100% de partículas AlB 12 apresentou um resultado intermediário, com tamanhos médios de grãos de 0,43 mm na liga Al-11Si-0,1Mg, no tempo de 5 minutos. A liga Al-11Si-0,1Mg refinada usando-se o refinador convencional Al-5Ti-1B apresentou tamanho médio de grão de 0,63 mm após 5 minutos de amostragem, o pior resultado quando comparado com os refinadores Al-4B com 100% de partículas AlB 2 e AlB 12 respectivamente. Palavras-chave:Refino de grão, alumínio, boro. ABSTRACTIn order to investigate the influence of AlB 2 and AlB 12 particles on the grain refining performance of an Al-4B master alloy in aluminum-silicon casting alloys, Aluminum Association TP-1 grain size tests were performed for varying concentrations of AlB 2 and AlB 12 . For the chemical characterization, optical emission spectrometry and energy dispersive spectrometry (EDS) were used. Grain sizes were measured by line intercept method using stereoscopic microscope. The results were compared with the conventional grain refiner Al-5Ti-1B. The aluminum-silicon alloy used was the Al-11Si-0.1Mg, common in the production of automotive wheels. The master alloy Al-4B with 100% of AlB 2 particles showed the best refining performance, providing average grain sizes of 0.26 mm in the alloy Al-11Si-0.1Mg after sampling time of 5 minutes. The alloy Al-4B with 100% of AlB 12 particles showed an intermediate result, with average sizes of 0.43 mm in the alloy Al-11Si-0.1Mg after sampling time of 5 minutes. The alloy Al-11Si-0,1Mg refined using the conventional grain refiner Al-5Ti-1B presented average grain size of 0,63 mm after 5 minutes of sampling time, the worst result compared with the refiners Al-4B with 100% of AlB 2 and AlB 12 particles respectively.
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